Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell

Carbon quantum dots (CQDs) and cadmium sulfide (CdS) QDs have previously been used to enhance the photovoltaic performance of ternary organic solar cells (OSCs). Different from the previous reports, both CQDs and CdS QDs synthesized via the wet chemical route were incorporated into the photoactive l...

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Main Authors: Issa, Nour Attallah, Tan, Sin Tee, Chia, Chin Hua, Lau, Kam Sheng, Hj Jumali, Mohammad Hafizuddin, Chong, Kok-Keong, Yap, Chi Chin
Format: Article
Language:English
Published: Elsevier B.V. 2025
Online Access:http://psasir.upm.edu.my/id/eprint/119139/
http://psasir.upm.edu.my/id/eprint/119139/1/119139.pdf
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author Issa, Nour Attallah
Tan, Sin Tee
Chia, Chin Hua
Lau, Kam Sheng
Hj Jumali, Mohammad Hafizuddin
Chong, Kok-Keong
Yap, Chi Chin
author_facet Issa, Nour Attallah
Tan, Sin Tee
Chia, Chin Hua
Lau, Kam Sheng
Hj Jumali, Mohammad Hafizuddin
Chong, Kok-Keong
Yap, Chi Chin
author_sort Issa, Nour Attallah
building UPM Institutional Repository
collection Online Access
description Carbon quantum dots (CQDs) and cadmium sulfide (CdS) QDs have previously been used to enhance the photovoltaic performance of ternary organic solar cells (OSCs). Different from the previous reports, both CQDs and CdS QDs synthesized via the wet chemical route were incorporated into the photoactive layers of poly(3-hexylthiophene) (P3HT):(6,6)-phenyl-C61-butyric acid methyl ester (PC61BM) to construct quaternary OSCs in this work. The effects of incorporating both CQDs and CdS QDs in photoactive layers on the photovoltaic performance of OSCs were investigated in detail. The structure of the OSCs was fluorine tin oxide (FTO)/ZnO/photoactive layer/Ag. The ZnO electron transport layer in nanorod arrays form was prepared using hydrothermal method, whereas the photoactive layer was deposited using spin coating technique. The OSCs with CdS QDs demonstrated a power conversion efficiency (PCE) of 2.87 %, an increment of 12 % in comparison to that without CdS QDs. The introduction of CdS QDs not only improves light absorption but also increases the exciton dissociation and electron transport.
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spelling upm-1191392025-08-06T07:51:54Z http://psasir.upm.edu.my/id/eprint/119139/ Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell Issa, Nour Attallah Tan, Sin Tee Chia, Chin Hua Lau, Kam Sheng Hj Jumali, Mohammad Hafizuddin Chong, Kok-Keong Yap, Chi Chin Carbon quantum dots (CQDs) and cadmium sulfide (CdS) QDs have previously been used to enhance the photovoltaic performance of ternary organic solar cells (OSCs). Different from the previous reports, both CQDs and CdS QDs synthesized via the wet chemical route were incorporated into the photoactive layers of poly(3-hexylthiophene) (P3HT):(6,6)-phenyl-C61-butyric acid methyl ester (PC61BM) to construct quaternary OSCs in this work. The effects of incorporating both CQDs and CdS QDs in photoactive layers on the photovoltaic performance of OSCs were investigated in detail. The structure of the OSCs was fluorine tin oxide (FTO)/ZnO/photoactive layer/Ag. The ZnO electron transport layer in nanorod arrays form was prepared using hydrothermal method, whereas the photoactive layer was deposited using spin coating technique. The OSCs with CdS QDs demonstrated a power conversion efficiency (PCE) of 2.87 %, an increment of 12 % in comparison to that without CdS QDs. The introduction of CdS QDs not only improves light absorption but also increases the exciton dissociation and electron transport. Elsevier B.V. 2025-02 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/119139/1/119139.pdf Issa, Nour Attallah and Tan, Sin Tee and Chia, Chin Hua and Lau, Kam Sheng and Hj Jumali, Mohammad Hafizuddin and Chong, Kok-Keong and Yap, Chi Chin (2025) Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell. Optical Materials, 159. art. no. 116638. pp. 1-5. ISSN 0925-3467; eISSN: 0925-3467 https://linkinghub.elsevier.com/retrieve/pii/S0925346724018214 10.1016/j.optmat.2024.116638
spellingShingle Issa, Nour Attallah
Tan, Sin Tee
Chia, Chin Hua
Lau, Kam Sheng
Hj Jumali, Mohammad Hafizuddin
Chong, Kok-Keong
Yap, Chi Chin
Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell
title Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell
title_full Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell
title_fullStr Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell
title_full_unstemmed Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell
title_short Incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell
title_sort incorporation of cadmium sulfide quantum dots in photoactive layer of quaternary organic solar cell
url http://psasir.upm.edu.my/id/eprint/119139/
http://psasir.upm.edu.my/id/eprint/119139/
http://psasir.upm.edu.my/id/eprint/119139/
http://psasir.upm.edu.my/id/eprint/119139/1/119139.pdf