Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite
Aqueous hybrid supercapacitors (HS) are a viable alternative to achieve low-cost, environmentally friendly, and safer energy storage technologies. Herein, lithium iron phosphate modified silicon and graphene derivatives (LFP/Si/graphene) are constructed as the cathode and graphene nanoplatelets (GNP...
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| Format: | Thesis |
| Language: | English |
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2024
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| Online Access: | http://psasir.upm.edu.my/id/eprint/118588/ http://psasir.upm.edu.my/id/eprint/118588/1/118588.pdf |
| _version_ | 1848867766568747008 |
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| author | Wan Mohd Abd Kalam, Wan Nadhirah |
| author_facet | Wan Mohd Abd Kalam, Wan Nadhirah |
| author_sort | Wan Mohd Abd Kalam, Wan Nadhirah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Aqueous hybrid supercapacitors (HS) are a viable alternative to achieve low-cost, environmentally friendly, and safer energy storage technologies. Herein, lithium iron phosphate modified silicon and graphene derivatives (LFP/Si/graphene) are constructed as the cathode and graphene nanoplatelets (GNPs) as the anode for an aqueous HS. The incorporation of GNPs and reduced graphene oxide (rGO), which is the source of graphene derivatives (graphene) in the composite, has played the role of an electronic conductivity enhancer for LFP and a binder for Si in the framework structure of the rGO film. Therefore, Si is able to perform its role effectively in avoiding surface instability issues and preventing the side reaction of LFP in an aqueous electrolyte. The electrochemical performance is evaluated in a 1 M Li2SO4 aqueous electrolyte that has been thoroughly deaerated with high-purified argon (Ar) gas to remove any dissolved oxygen that might interfere with the analysis. The Ar blanketing in the electrolyte intensified the electrochemical performance by 60% as compared to the Ar-free electrolyte, proving that the presence of Ar has offered a more stable electrolyte to protect the electrode surfaces from contaminants and impurities during charging and discharging processes. The coated LFP by 0.5 w/w% Si with incorporation of graphene (LFP/Si0.5/graphene) for electronic conductivity enhancement in Swagelok-type cells has an exceptional specific capacitance of 272.6 F g-1 and a highly improved cycle life, which shows 87.2% capacitance retention after 5200 cycles. Moreover, a different assembly of a close-to-current commercial format of roll-type cell is also studied, which exhibits a slightly higher specific capacitance of 301.3 F g-1 with energy and power density of 35.62 Wh kg-1 with 922.53 W kg-1, respectively. Therefore, both cell configurations of Swagelok-type and roll-type, using LFP/Si0.5/graphene, have displayed promising applications of the HS, which have the potential to slowly build themselves into a vital role in hybrid-electric technology. |
| first_indexed | 2025-11-15T14:41:43Z |
| format | Thesis |
| id | upm-118588 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T14:41:43Z |
| publishDate | 2024 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1185882025-08-04T08:10:56Z http://psasir.upm.edu.my/id/eprint/118588/ Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite Wan Mohd Abd Kalam, Wan Nadhirah Aqueous hybrid supercapacitors (HS) are a viable alternative to achieve low-cost, environmentally friendly, and safer energy storage technologies. Herein, lithium iron phosphate modified silicon and graphene derivatives (LFP/Si/graphene) are constructed as the cathode and graphene nanoplatelets (GNPs) as the anode for an aqueous HS. The incorporation of GNPs and reduced graphene oxide (rGO), which is the source of graphene derivatives (graphene) in the composite, has played the role of an electronic conductivity enhancer for LFP and a binder for Si in the framework structure of the rGO film. Therefore, Si is able to perform its role effectively in avoiding surface instability issues and preventing the side reaction of LFP in an aqueous electrolyte. The electrochemical performance is evaluated in a 1 M Li2SO4 aqueous electrolyte that has been thoroughly deaerated with high-purified argon (Ar) gas to remove any dissolved oxygen that might interfere with the analysis. The Ar blanketing in the electrolyte intensified the electrochemical performance by 60% as compared to the Ar-free electrolyte, proving that the presence of Ar has offered a more stable electrolyte to protect the electrode surfaces from contaminants and impurities during charging and discharging processes. The coated LFP by 0.5 w/w% Si with incorporation of graphene (LFP/Si0.5/graphene) for electronic conductivity enhancement in Swagelok-type cells has an exceptional specific capacitance of 272.6 F g-1 and a highly improved cycle life, which shows 87.2% capacitance retention after 5200 cycles. Moreover, a different assembly of a close-to-current commercial format of roll-type cell is also studied, which exhibits a slightly higher specific capacitance of 301.3 F g-1 with energy and power density of 35.62 Wh kg-1 with 922.53 W kg-1, respectively. Therefore, both cell configurations of Swagelok-type and roll-type, using LFP/Si0.5/graphene, have displayed promising applications of the HS, which have the potential to slowly build themselves into a vital role in hybrid-electric technology. 2024-02 Thesis NonPeerReviewed text en http://psasir.upm.edu.my/id/eprint/118588/1/118588.pdf Wan Mohd Abd Kalam, Wan Nadhirah (2024) Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite. Masters thesis, Universiti Putra Malaysia. http://ethesis.upm.edu.my/id/eprint/18399 Supercapacitors Graphene - Industrial applications Silicon - Electric properties |
| spellingShingle | Supercapacitors Graphene - Industrial applications Silicon - Electric properties Wan Mohd Abd Kalam, Wan Nadhirah Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite |
| title | Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite |
| title_full | Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite |
| title_fullStr | Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite |
| title_full_unstemmed | Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite |
| title_short | Electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite |
| title_sort | electrochemical performance of aqueous hybrid supercapacitor based on lithium iron phosphate/silicon/graphene composite |
| topic | Supercapacitors Graphene - Industrial applications Silicon - Electric properties |
| url | http://psasir.upm.edu.my/id/eprint/118588/ http://psasir.upm.edu.my/id/eprint/118588/ http://psasir.upm.edu.my/id/eprint/118588/1/118588.pdf |