Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity

Casein (CN) is a common allergen that is challenging to avoid in modern foods. The effect of cold argon plasma (CAP) on reducing CN antigenicity was investigated, focusing on alterations in epitope structure and sequence. CAP mainly contains hydroxyl radicals (∙OH). After a 12-min CAP treatment, the...

Full description

Bibliographic Details
Main Authors: Cai, Ruiyi, Tan, Chin-Ping, Lai, Oi-Ming, Dang, Yali, Liu, Aiming, Choeng, Ling-zhi, Pan, Daodong, Du, Lihui
Format: Article
Language:English
Published: Elsevier Ltd 2025
Online Access:http://psasir.upm.edu.my/id/eprint/118539/
http://psasir.upm.edu.my/id/eprint/118539/1/118539.pdf
_version_ 1848867539459768320
author Cai, Ruiyi
Tan, Chin-Ping
Lai, Oi-Ming
Dang, Yali
Liu, Aiming
Choeng, Ling-zhi
Pan, Daodong
Du, Lihui
author_facet Cai, Ruiyi
Tan, Chin-Ping
Lai, Oi-Ming
Dang, Yali
Liu, Aiming
Choeng, Ling-zhi
Pan, Daodong
Du, Lihui
author_sort Cai, Ruiyi
building UPM Institutional Repository
collection Online Access
description Casein (CN) is a common allergen that is challenging to avoid in modern foods. The effect of cold argon plasma (CAP) on reducing CN antigenicity was investigated, focusing on alterations in epitope structure and sequence. CAP mainly contains hydroxyl radicals (∙OH). After a 12-min CAP treatment, the result of ELISA demonstrated an 80.46 % reduction in antigenicity. Transmission electron microscopy and electrophoresis revealed that certain CN aggregated, while multispectral analysis indicated that part of CN was fragmented into smaller peptides. The predictive 3D model suggested the disruption of linear epitopes located in the α-helix region might contribute to the reduced allergenicity. The peptide sequences were compared to the linear epitopes predicted by immunoinformatics approaches, revealing some reduction or breakage of key allergic sequences. Meanwhile, amino acids with aromatic side chains and hydrophobic groups were susceptible to CAP-induced modifications. This investigation demonstrated CAP could be beneficial for processing hypoallergenic foods.
first_indexed 2025-11-15T14:38:06Z
format Article
id upm-118539
institution Universiti Putra Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T14:38:06Z
publishDate 2025
publisher Elsevier Ltd
recordtype eprints
repository_type Digital Repository
spelling upm-1185392025-07-16T03:06:15Z http://psasir.upm.edu.my/id/eprint/118539/ Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity Cai, Ruiyi Tan, Chin-Ping Lai, Oi-Ming Dang, Yali Liu, Aiming Choeng, Ling-zhi Pan, Daodong Du, Lihui Casein (CN) is a common allergen that is challenging to avoid in modern foods. The effect of cold argon plasma (CAP) on reducing CN antigenicity was investigated, focusing on alterations in epitope structure and sequence. CAP mainly contains hydroxyl radicals (∙OH). After a 12-min CAP treatment, the result of ELISA demonstrated an 80.46 % reduction in antigenicity. Transmission electron microscopy and electrophoresis revealed that certain CN aggregated, while multispectral analysis indicated that part of CN was fragmented into smaller peptides. The predictive 3D model suggested the disruption of linear epitopes located in the α-helix region might contribute to the reduced allergenicity. The peptide sequences were compared to the linear epitopes predicted by immunoinformatics approaches, revealing some reduction or breakage of key allergic sequences. Meanwhile, amino acids with aromatic side chains and hydrophobic groups were susceptible to CAP-induced modifications. This investigation demonstrated CAP could be beneficial for processing hypoallergenic foods. Elsevier Ltd 2025-03 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/118539/1/118539.pdf Cai, Ruiyi and Tan, Chin-Ping and Lai, Oi-Ming and Dang, Yali and Liu, Aiming and Choeng, Ling-zhi and Pan, Daodong and Du, Lihui (2025) Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity. Food Chemistry, 468. art. no. 142408. pp. 1-13. ISSN 0308-8146; eISSN: 1873-7072 https://linkinghub.elsevier.com/retrieve/pii/S0308814624040585 10.1016/j.foodchem.2024.142408
spellingShingle Cai, Ruiyi
Tan, Chin-Ping
Lai, Oi-Ming
Dang, Yali
Liu, Aiming
Choeng, Ling-zhi
Pan, Daodong
Du, Lihui
Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity
title Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity
title_full Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity
title_fullStr Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity
title_full_unstemmed Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity
title_short Cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity
title_sort cold argon plasma-induced aggregated and non-aggregated structural changes in casein and peptidomic insights into allergenicity
url http://psasir.upm.edu.my/id/eprint/118539/
http://psasir.upm.edu.my/id/eprint/118539/
http://psasir.upm.edu.my/id/eprint/118539/
http://psasir.upm.edu.my/id/eprint/118539/1/118539.pdf