Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature

In recent decades, poorly insulated windows have increased the energy consumption of heating and cooling systems, thus contributing to excessive carbon dioxide emissions and other related pollution issues. From this perspective, the electrochromic (EC) windows could be a tangible solution as the ind...

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Main Authors: Tan, Ming-Yue, Thien, Gregory Soon How, Tan, Kar-Ban, Murthy, H. C. Ananda, Chan, Kah-Yoong
Format: Article
Language:English
Published: Nature Research 2025
Online Access:http://psasir.upm.edu.my/id/eprint/118390/
http://psasir.upm.edu.my/id/eprint/118390/1/118390.pdf
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author Tan, Ming-Yue
Thien, Gregory Soon How
Tan, Kar-Ban
Murthy, H. C. Ananda
Chan, Kah-Yoong
author_facet Tan, Ming-Yue
Thien, Gregory Soon How
Tan, Kar-Ban
Murthy, H. C. Ananda
Chan, Kah-Yoong
author_sort Tan, Ming-Yue
building UPM Institutional Repository
collection Online Access
description In recent decades, poorly insulated windows have increased the energy consumption of heating and cooling systems, thus contributing to excessive carbon dioxide emissions and other related pollution issues. From this perspective, the electrochromic (EC) windows could be a tangible solution as the indoor conditions are highly controllable by these smart devices even at a low applied voltage. Literally, vanadium pentoxide (V2O5) is a renowned candidate for the EC application due to its multicolor appearance and substantial lithium insertion capacity. Despite the growing interest in V2O5 thin films, only limited literature study is available for V2O5 films specifically the annealing effects of these films at lower temperatures (< 300 °C). It is noteworthy that a low temperature is advantageous for glass-based EC devices, as it prevents deformation, cracking, and structural damage to the transparent conductive glass. In this study, V2O5 thin films were fabricated using the sol–gel spin coating technique prior to annealing over the temperature range of 100–300 °C. Subsequently, V2O5 thin films were assembled into a device form to analyze their EC characteristics. The V2O5 device, featuring thin film annealed at 200 °C, demonstrated excellent EC performance with high optical contrast of 42.32%, high coloration efficiency (CE) of 34.93 cm2/C, as well as rapid coloring and bleaching times of 0.4 s and 3 s, respectively. These results shed light on the importance of annealing temperature control towards the EC performance of V2O5 devices for future applications.
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spelling upm-1183902025-07-09T03:28:00Z http://psasir.upm.edu.my/id/eprint/118390/ Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature Tan, Ming-Yue Thien, Gregory Soon How Tan, Kar-Ban Murthy, H. C. Ananda Chan, Kah-Yoong In recent decades, poorly insulated windows have increased the energy consumption of heating and cooling systems, thus contributing to excessive carbon dioxide emissions and other related pollution issues. From this perspective, the electrochromic (EC) windows could be a tangible solution as the indoor conditions are highly controllable by these smart devices even at a low applied voltage. Literally, vanadium pentoxide (V2O5) is a renowned candidate for the EC application due to its multicolor appearance and substantial lithium insertion capacity. Despite the growing interest in V2O5 thin films, only limited literature study is available for V2O5 films specifically the annealing effects of these films at lower temperatures (< 300 °C). It is noteworthy that a low temperature is advantageous for glass-based EC devices, as it prevents deformation, cracking, and structural damage to the transparent conductive glass. In this study, V2O5 thin films were fabricated using the sol–gel spin coating technique prior to annealing over the temperature range of 100–300 °C. Subsequently, V2O5 thin films were assembled into a device form to analyze their EC characteristics. The V2O5 device, featuring thin film annealed at 200 °C, demonstrated excellent EC performance with high optical contrast of 42.32%, high coloration efficiency (CE) of 34.93 cm2/C, as well as rapid coloring and bleaching times of 0.4 s and 3 s, respectively. These results shed light on the importance of annealing temperature control towards the EC performance of V2O5 devices for future applications. Nature Research 2025-01-07 Article PeerReviewed text en cc_by_nc_nd_4 http://psasir.upm.edu.my/id/eprint/118390/1/118390.pdf Tan, Ming-Yue and Thien, Gregory Soon How and Tan, Kar-Ban and Murthy, H. C. Ananda and Chan, Kah-Yoong (2025) Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature. Scientific Reports, 15. art. no. 1184. pp. 1-14. ISSN 2045-2322; eISSN: 2045-2322 https://www.nature.com/articles/s41598-024-85014-7?error=cookies_not_supported&code=d8c715ad-194c-4958-b58d-a8c629cf29b0 10.1038/s41598-024-85014-7
spellingShingle Tan, Ming-Yue
Thien, Gregory Soon How
Tan, Kar-Ban
Murthy, H. C. Ananda
Chan, Kah-Yoong
Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature
title Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature
title_full Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature
title_fullStr Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature
title_full_unstemmed Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature
title_short Investigation of electrochromic performances of multicolor V2O5 devices fabricated at low processing temperature
title_sort investigation of electrochromic performances of multicolor v2o5 devices fabricated at low processing temperature
url http://psasir.upm.edu.my/id/eprint/118390/
http://psasir.upm.edu.my/id/eprint/118390/
http://psasir.upm.edu.my/id/eprint/118390/
http://psasir.upm.edu.my/id/eprint/118390/1/118390.pdf