Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia

This study investigates the physicochemical parameters of water, their association with inorganic phosphate fractions, and the sorption capacity of sediments. Water and sediment samples were collected from upstream, midstream, and downstream sections between November 2022 and June 2023. The water sa...

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Main Authors: Jega, Bilyaminu Garba, Mustafa, Muskhazli, Rajaram, Micheal Charles, Abd Aziz, Nor Azwady, Wan Solahudin, Wan Mohd Syazwan, Hashim, Noor Haza Fazlin, Mohd Fazli, Bashirah
Format: Article
Language:English
Published: Universiti Putra Malaysia Press 2025
Online Access:http://psasir.upm.edu.my/id/eprint/117763/
http://psasir.upm.edu.my/id/eprint/117763/1/117763.pdf
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author Jega, Bilyaminu Garba
Mustafa, Muskhazli
Rajaram, Micheal Charles
Abd Aziz, Nor Azwady
Wan Solahudin, Wan Mohd Syazwan
Hashim, Noor Haza Fazlin
Mohd Fazli, Bashirah
author_facet Jega, Bilyaminu Garba
Mustafa, Muskhazli
Rajaram, Micheal Charles
Abd Aziz, Nor Azwady
Wan Solahudin, Wan Mohd Syazwan
Hashim, Noor Haza Fazlin
Mohd Fazli, Bashirah
author_sort Jega, Bilyaminu Garba
building UPM Institutional Repository
collection Online Access
description This study investigates the physicochemical parameters of water, their association with inorganic phosphate fractions, and the sorption capacity of sediments. Water and sediment samples were collected from upstream, midstream, and downstream sections between November 2022 and June 2023. The water samples were analysed according to the American Public Health Association (APHA) guidelines for physicochemical parameters. Inorganic phosphate fractions in the sediments were quantified using the molybdenum blue colourimetric method. Sediment phosphate sorption capacity was assessed by measuring the resulting filtrate and applying regression correlation and Langmuir isotherm models to determine the relationships among the sediment samples. Sediment analysis of inorganic phosphorous fractions revealed varying percentages of Ca-P (32.6%), Rs-P (38.3%), and Fe-P (48.4%) dominating the upstream, midstream, and downstream sections, respectively. Sediment phosphate adsorption varied between sections (upstream: 4.00 to 18.21 mg/g vs. midstream: 4.36 to 21.10 mg/g vs downstream: 4.00 to 12.98 mg/g), with no significant differences between streams at specific phosphate concentrations. However, all the sections displayed a saturation point of approximately 20–25 mg/l. The Langmuir isotherm parameters accurately described P adsorption onto Langat River sediments, as indicated by the moderately high R2 values for Qmax and RL. The downstream section of the Langat River had elevated levels of EC, COD and SRP parameters and Ex-P, Al-P, Fe-P, and Ca-P fractions, except for the Rs-P fraction that dominated the midstream section, indicating collective effects of anthropogenic activities. Therefore, strict regulations to improve wastewater treatment and promote sustainable wastewater management are essential for reducing inorganic phosphorus pollution in the Langat River and protecting water quality.
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spelling upm-1177632025-06-11T07:31:56Z http://psasir.upm.edu.my/id/eprint/117763/ Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia Jega, Bilyaminu Garba Mustafa, Muskhazli Rajaram, Micheal Charles Abd Aziz, Nor Azwady Wan Solahudin, Wan Mohd Syazwan Hashim, Noor Haza Fazlin Mohd Fazli, Bashirah This study investigates the physicochemical parameters of water, their association with inorganic phosphate fractions, and the sorption capacity of sediments. Water and sediment samples were collected from upstream, midstream, and downstream sections between November 2022 and June 2023. The water samples were analysed according to the American Public Health Association (APHA) guidelines for physicochemical parameters. Inorganic phosphate fractions in the sediments were quantified using the molybdenum blue colourimetric method. Sediment phosphate sorption capacity was assessed by measuring the resulting filtrate and applying regression correlation and Langmuir isotherm models to determine the relationships among the sediment samples. Sediment analysis of inorganic phosphorous fractions revealed varying percentages of Ca-P (32.6%), Rs-P (38.3%), and Fe-P (48.4%) dominating the upstream, midstream, and downstream sections, respectively. Sediment phosphate adsorption varied between sections (upstream: 4.00 to 18.21 mg/g vs. midstream: 4.36 to 21.10 mg/g vs downstream: 4.00 to 12.98 mg/g), with no significant differences between streams at specific phosphate concentrations. However, all the sections displayed a saturation point of approximately 20–25 mg/l. The Langmuir isotherm parameters accurately described P adsorption onto Langat River sediments, as indicated by the moderately high R2 values for Qmax and RL. The downstream section of the Langat River had elevated levels of EC, COD and SRP parameters and Ex-P, Al-P, Fe-P, and Ca-P fractions, except for the Rs-P fraction that dominated the midstream section, indicating collective effects of anthropogenic activities. Therefore, strict regulations to improve wastewater treatment and promote sustainable wastewater management are essential for reducing inorganic phosphorus pollution in the Langat River and protecting water quality. Universiti Putra Malaysia Press 2025-01-23 Article PeerReviewed text en cc_by_nc_nd_4 http://psasir.upm.edu.my/id/eprint/117763/1/117763.pdf Jega, Bilyaminu Garba and Mustafa, Muskhazli and Rajaram, Micheal Charles and Abd Aziz, Nor Azwady and Wan Solahudin, Wan Mohd Syazwan and Hashim, Noor Haza Fazlin and Mohd Fazli, Bashirah (2025) Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia. Pertanika Journal of Science and Technology, 33 (1). art. no. JST-5081-2024. pp. 355-377. ISSN 0128-7680; eISSN: 2231-8526 http://www.pertanika.upm.edu.my/pjst/browse/regular-issue?article=JST-5081-2024 10.47836/pjst.33.1.16
spellingShingle Jega, Bilyaminu Garba
Mustafa, Muskhazli
Rajaram, Micheal Charles
Abd Aziz, Nor Azwady
Wan Solahudin, Wan Mohd Syazwan
Hashim, Noor Haza Fazlin
Mohd Fazli, Bashirah
Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia
title Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia
title_full Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia
title_fullStr Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia
title_full_unstemmed Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia
title_short Inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in Langat River, Selangor Malaysia
title_sort inorganic phosphorus fractions and sorption capacity of sediments correlated with physicochemical parameters of water in langat river, selangor malaysia
url http://psasir.upm.edu.my/id/eprint/117763/
http://psasir.upm.edu.my/id/eprint/117763/
http://psasir.upm.edu.my/id/eprint/117763/
http://psasir.upm.edu.my/id/eprint/117763/1/117763.pdf