Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites

The efficient inclusion of GNPs (graphene nanoplatelets) as an effective nano-fillers for green polymer matrices produced with 28% of carbon originating from biomass tends to significantly improve mechanical and thermal properties. In the present work, green epoxy nanocomposites with low loading of...

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Main Authors: Salit @ Sinon, Mohd Sapuan, Jameel, Yusuf, Hassan, Mohd Roshdi, Rashid, Umer, Ilyas, Ra
Format: Article
Published: John Wiley & Sons, Inc. 2023
Online Access:http://psasir.upm.edu.my/id/eprint/117654/
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author Salit @ Sinon, Mohd Sapuan
Jameel, Yusuf
Hassan, Mohd Roshdi
Rashid, Umer
Ilyas, Ra
author_facet Salit @ Sinon, Mohd Sapuan
Jameel, Yusuf
Hassan, Mohd Roshdi
Rashid, Umer
Ilyas, Ra
author_sort Salit @ Sinon, Mohd Sapuan
building UPM Institutional Repository
collection Online Access
description The efficient inclusion of GNPs (graphene nanoplatelets) as an effective nano-fillers for green polymer matrices produced with 28% of carbon originating from biomass tends to significantly improve mechanical and thermal properties. In the present work, green epoxy nanocomposites with low loading of (0.1, 0.25, and 0.5) wt% of the GNPs were made using a solution blending technique using acetone as the solvent. In mechanical stirring, the ultrasonic bath was used to ensure the efficient dispersion of GNPs within green epoxy. The resulting nanocomposites were comprehensively characterized and compared to unfilled green epoxy. Different tools were used to appraise morphological, thermal, thermo-mechanical, and mechanical behavior. The results confirmed through FE-SEM showed an optimal dispersion of GNPs with nanocomposites. The thermal degradation temperature (Td) of GNPs curve with 0.25 wt% loading was shifted toward higher temperature (from 336°C to 342°C) due to low percentage of loading of GNPs which showed an enhance thermal stability of polymer matrix with 0.25 wt% loading. The mechanical results were also in lined with previously published literature, in the tensile test 6.45% and hardness 13.3% increment was achieved. Overall, the results underscored significant improvements in green nanocomposite performance with low wt% of GNPs.
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spelling upm-1176542025-06-04T04:35:31Z http://psasir.upm.edu.my/id/eprint/117654/ Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites Salit @ Sinon, Mohd Sapuan Jameel, Yusuf Hassan, Mohd Roshdi Rashid, Umer Ilyas, Ra The efficient inclusion of GNPs (graphene nanoplatelets) as an effective nano-fillers for green polymer matrices produced with 28% of carbon originating from biomass tends to significantly improve mechanical and thermal properties. In the present work, green epoxy nanocomposites with low loading of (0.1, 0.25, and 0.5) wt% of the GNPs were made using a solution blending technique using acetone as the solvent. In mechanical stirring, the ultrasonic bath was used to ensure the efficient dispersion of GNPs within green epoxy. The resulting nanocomposites were comprehensively characterized and compared to unfilled green epoxy. Different tools were used to appraise morphological, thermal, thermo-mechanical, and mechanical behavior. The results confirmed through FE-SEM showed an optimal dispersion of GNPs with nanocomposites. The thermal degradation temperature (Td) of GNPs curve with 0.25 wt% loading was shifted toward higher temperature (from 336°C to 342°C) due to low percentage of loading of GNPs which showed an enhance thermal stability of polymer matrix with 0.25 wt% loading. The mechanical results were also in lined with previously published literature, in the tensile test 6.45% and hardness 13.3% increment was achieved. Overall, the results underscored significant improvements in green nanocomposite performance with low wt% of GNPs. John Wiley & Sons, Inc. 2023-11-10 Article PeerReviewed Salit @ Sinon, Mohd Sapuan and Jameel, Yusuf and Hassan, Mohd Roshdi and Rashid, Umer and Ilyas, Ra (2023) Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites. Polymer Composites, 45 (3). pp. 1998-2011. ISSN 0272-8397; eISSN: 1548-0569 https://4spepublications.onlinelibrary.wiley.com/doi/10.1002/pc.27900 10.1002/pc.27900
spellingShingle Salit @ Sinon, Mohd Sapuan
Jameel, Yusuf
Hassan, Mohd Roshdi
Rashid, Umer
Ilyas, Ra
Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites
title Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites
title_full Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites
title_fullStr Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites
title_full_unstemmed Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites
title_short Thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites
title_sort thermal, mechanical, thermo-mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites
url http://psasir.upm.edu.my/id/eprint/117654/
http://psasir.upm.edu.my/id/eprint/117654/
http://psasir.upm.edu.my/id/eprint/117654/