Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate
In the title compound, C14H14N2S 3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragmen...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Published: |
2003
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/116369/ |
| _version_ | 1848866987505090560 |
|---|---|
| author | Chan, Mun-Hoe Eddy Crouse, Karen A. Tarafder, M. T. H. Yamin, Bohari. M. |
| author_facet | Chan, Mun-Hoe Eddy Crouse, Karen A. Tarafder, M. T. H. Yamin, Bohari. M. |
| author_sort | Chan, Mun-Hoe Eddy |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | In the title compound, C14H14N2S 3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragments, respectively. In the crystal structure, the molecules are linked by N-H⋯S hydrogen bonds between the amino group and the thiono S atoms and are arranged as dimers parallel to ab face. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| first_indexed | 2025-11-15T14:29:20Z |
| format | Article |
| id | upm-116369 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T14:29:20Z |
| publishDate | 2003 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1163692025-03-27T05:04:09Z http://psasir.upm.edu.my/id/eprint/116369/ Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate Chan, Mun-Hoe Eddy Crouse, Karen A. Tarafder, M. T. H. Yamin, Bohari. M. In the title compound, C14H14N2S 3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragments, respectively. In the crystal structure, the molecules are linked by N-H⋯S hydrogen bonds between the amino group and the thiono S atoms and are arranged as dimers parallel to ab face. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved. 2003 Article PeerReviewed Chan, Mun-Hoe Eddy and Crouse, Karen A. and Tarafder, M. T. H. and Yamin, Bohari. M. (2003) Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 59 (5). ISSN 1600-5368; eISSN: 1600-5368 https://journals.iucr.org/paper?S1600536803007517 10.1107/S1600536803007517 |
| spellingShingle | Chan, Mun-Hoe Eddy Crouse, Karen A. Tarafder, M. T. H. Yamin, Bohari. M. Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate |
| title | Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate |
| title_full | Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate |
| title_fullStr | Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate |
| title_full_unstemmed | Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate |
| title_short | Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate |
| title_sort | benzyl n-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate |
| url | http://psasir.upm.edu.my/id/eprint/116369/ http://psasir.upm.edu.my/id/eprint/116369/ http://psasir.upm.edu.my/id/eprint/116369/ |