Composition of crystals of palm olein formed at room temperature

The composition of purified plam olein crystals formed at room temperature (25°C) was identified in this study. Two peaks were obtained when the crystals were analyzed by reverse-phase high-performance liquid chromatography (RP-HPLC). The retention times of these peaks suggested that they were not t...

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Main Authors: Swe, P.Z., Cheman, Y.B., Ghazali, H.M.
Format: Article
Published: Springer-Verlag 1995
Online Access:http://psasir.upm.edu.my/id/eprint/115856/
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author Swe, P.Z.
Cheman, Y.B.
Ghazali, H.M.
author_facet Swe, P.Z.
Cheman, Y.B.
Ghazali, H.M.
author_sort Swe, P.Z.
building UPM Institutional Repository
collection Online Access
description The composition of purified plam olein crystals formed at room temperature (25°C) was identified in this study. Two peaks were obtained when the crystals were analyzed by reverse-phase high-performance liquid chromatography (RP-HPLC). The retention times of these peaks suggested that they were not triglycerides. Gas-liquid chromatography of fatty acid methyl ester analysis of the crystals showed the presence of C16, C18:0, and C18:1 fatty acids. Further analysis by gas-liquid chromatography of carbon number, after collecting the fractions from RP-HPLC, concluded that the major peak A was 1,3-dipalmito-glycerol. The minor peak B was tentatively identified as 1-palmito-3-stearo-glycerol and/or 1-palmito-3-oleo-glycerol due to unavailability of respective standard glycerides. The differential scanning calorimetry thermogram of the crystals show that A and B were indeed the high melting glycerides, with melting and crystallization points of 70.4 and 53.8°C, respectively.
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spelling upm-1158562025-03-14T00:23:41Z http://psasir.upm.edu.my/id/eprint/115856/ Composition of crystals of palm olein formed at room temperature Swe, P.Z. Cheman, Y.B. Ghazali, H.M. The composition of purified plam olein crystals formed at room temperature (25°C) was identified in this study. Two peaks were obtained when the crystals were analyzed by reverse-phase high-performance liquid chromatography (RP-HPLC). The retention times of these peaks suggested that they were not triglycerides. Gas-liquid chromatography of fatty acid methyl ester analysis of the crystals showed the presence of C16, C18:0, and C18:1 fatty acids. Further analysis by gas-liquid chromatography of carbon number, after collecting the fractions from RP-HPLC, concluded that the major peak A was 1,3-dipalmito-glycerol. The minor peak B was tentatively identified as 1-palmito-3-stearo-glycerol and/or 1-palmito-3-oleo-glycerol due to unavailability of respective standard glycerides. The differential scanning calorimetry thermogram of the crystals show that A and B were indeed the high melting glycerides, with melting and crystallization points of 70.4 and 53.8°C, respectively. Springer-Verlag 1995 Article PeerReviewed Swe, P.Z. and Cheman, Y.B. and Ghazali, H.M. (1995) Composition of crystals of palm olein formed at room temperature. Journal of the American Oil Chemists' Society, 72 (3). pp. 343-347. ISSN 1558-9331; eISSN: 0003-021X https://aocs.onlinelibrary.wiley.com/doi/10.1007/BF02541094 10.1007/BF02541094
spellingShingle Swe, P.Z.
Cheman, Y.B.
Ghazali, H.M.
Composition of crystals of palm olein formed at room temperature
title Composition of crystals of palm olein formed at room temperature
title_full Composition of crystals of palm olein formed at room temperature
title_fullStr Composition of crystals of palm olein formed at room temperature
title_full_unstemmed Composition of crystals of palm olein formed at room temperature
title_short Composition of crystals of palm olein formed at room temperature
title_sort composition of crystals of palm olein formed at room temperature
url http://psasir.upm.edu.my/id/eprint/115856/
http://psasir.upm.edu.my/id/eprint/115856/
http://psasir.upm.edu.my/id/eprint/115856/