Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr
The compositional ranges of Bi4V2O11 solid solutions containing Co, Cu, Zn, Ca and Sr have been determined by means of a phase diagram study at solidus temperatures. Depending on the size of the divalent cation, at least three and probably four mechanisms for accommodating variable cation content ha...
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| Language: | English |
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Royal Society of Chemistry
1994
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| Online Access: | http://psasir.upm.edu.my/id/eprint/115596/ http://psasir.upm.edu.my/id/eprint/115596/1/115596.pdf |
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| author | Chnoong, Kheng Lee Goik, See Lim West, Anthony R. |
| author_facet | Chnoong, Kheng Lee Goik, See Lim West, Anthony R. |
| author_sort | Chnoong, Kheng Lee |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The compositional ranges of Bi4V2O11 solid solutions containing Co, Cu, Zn, Ca and Sr have been determined by means of a phase diagram study at solidus temperatures. Depending on the size of the divalent cation, at least three and probably four mechanisms for accommodating variable cation content have been identified. These are: V ⇌ Bi, V ⇌ M, Bi ⇌ M and probably, formation of interstitial M. Most previous studies have focused on the single mechanism V ⇌ M whereas, in fact, the solid solutions are shown to be far more varied and extensive than previously supposed. |
| first_indexed | 2025-11-15T14:26:40Z |
| format | Article |
| id | upm-115596 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T14:26:40Z |
| publishDate | 1994 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
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| spelling | upm-1155962025-07-08T04:13:41Z http://psasir.upm.edu.my/id/eprint/115596/ Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr Chnoong, Kheng Lee Goik, See Lim West, Anthony R. The compositional ranges of Bi4V2O11 solid solutions containing Co, Cu, Zn, Ca and Sr have been determined by means of a phase diagram study at solidus temperatures. Depending on the size of the divalent cation, at least three and probably four mechanisms for accommodating variable cation content have been identified. These are: V ⇌ Bi, V ⇌ M, Bi ⇌ M and probably, formation of interstitial M. Most previous studies have focused on the single mechanism V ⇌ M whereas, in fact, the solid solutions are shown to be far more varied and extensive than previously supposed. Royal Society of Chemistry 1994 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/115596/1/115596.pdf Chnoong, Kheng Lee and Goik, See Lim and West, Anthony R. (1994) Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr. Journal of Materials Chemistry, 4 (9). pp. 1441-1444. ISSN 0959-9428; eISSN: 0959-9428 https://pubs.rsc.org/en/content/articlelanding/1994/jm/jm9940401441 10.1039/jm9940401441 |
| spellingShingle | Chnoong, Kheng Lee Goik, See Lim West, Anthony R. Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr |
| title | Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr |
| title_full | Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr |
| title_fullStr | Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr |
| title_full_unstemmed | Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr |
| title_short | Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr |
| title_sort | phase diagrams and stoichiometries of the solid electrolytes, bi 4v2o11: m, m = co, cu, zn, ca, sr |
| url | http://psasir.upm.edu.my/id/eprint/115596/ http://psasir.upm.edu.my/id/eprint/115596/ http://psasir.upm.edu.my/id/eprint/115596/ http://psasir.upm.edu.my/id/eprint/115596/1/115596.pdf |