Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona

Diacylglycerol–based nanoparticles are promising bioactive delivery systems. However, limited understanding of their interaction with biological entities restricts their clinical use. This study investigated the protein corona formed on medium and long chain diacylglycerol (MLCD)-based solid lipid n...

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Main Authors: Chen, Canfeng, Alfredo, Ying Ye, Lee, Yee Ying, Tan, Chin Ping, Wang, Yong, Qiu, Chaoying
Format: Article
Language:English
Published: Elsevier 2024
Online Access:http://psasir.upm.edu.my/id/eprint/115557/
http://psasir.upm.edu.my/id/eprint/115557/1/115557.pdf
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author Chen, Canfeng
Alfredo, Ying Ye
Lee, Yee Ying
Tan, Chin Ping
Wang, Yong
Qiu, Chaoying
author_facet Chen, Canfeng
Alfredo, Ying Ye
Lee, Yee Ying
Tan, Chin Ping
Wang, Yong
Qiu, Chaoying
author_sort Chen, Canfeng
building UPM Institutional Repository
collection Online Access
description Diacylglycerol–based nanoparticles are promising bioactive delivery systems. However, limited understanding of their interaction with biological entities restricts their clinical use. This study investigated the protein corona formed on medium and long chain diacylglycerol (MLCD)-based solid lipid nanoparticles (NPs) modified by Polyoxethylene stearate (PEG) and compared to glyceryl tristearate (TG) and cetyl palmitate (CP) nanoparticles. Bovine serum albumin (BSA) formed corona with MLCD NPs through hydrophobic interactions and hydrogen bonding, contributing to a decrease in α–helix, an increase in β–sheet and a change in the microenvironment of Tyr residues. Owing to higher lipid hydrophilicity, MLCD NPs showed a much lower affinity for BSA than TG and CP NPs, and the binding constant with BSA was increased for larger NPs. PEG modification and the protein corona reduced the uptake of NPs by macrophages but exerted little influence on B16 cell. Among the NPs with different lipid core, the MLCD NPs showed a lower macrophages cell uptake but higher B16 cell uptake, suggesting a longer circulation time in blood but higher cancer cell internalization. This work shed light on the interactions between MLCD NPs and proteins, which is significant for application as nanocarriers with improved biological efficacy.
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spelling upm-1155572025-04-21T02:53:45Z http://psasir.upm.edu.my/id/eprint/115557/ Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona Chen, Canfeng Alfredo, Ying Ye Lee, Yee Ying Tan, Chin Ping Wang, Yong Qiu, Chaoying Diacylglycerol–based nanoparticles are promising bioactive delivery systems. However, limited understanding of their interaction with biological entities restricts their clinical use. This study investigated the protein corona formed on medium and long chain diacylglycerol (MLCD)-based solid lipid nanoparticles (NPs) modified by Polyoxethylene stearate (PEG) and compared to glyceryl tristearate (TG) and cetyl palmitate (CP) nanoparticles. Bovine serum albumin (BSA) formed corona with MLCD NPs through hydrophobic interactions and hydrogen bonding, contributing to a decrease in α–helix, an increase in β–sheet and a change in the microenvironment of Tyr residues. Owing to higher lipid hydrophilicity, MLCD NPs showed a much lower affinity for BSA than TG and CP NPs, and the binding constant with BSA was increased for larger NPs. PEG modification and the protein corona reduced the uptake of NPs by macrophages but exerted little influence on B16 cell. Among the NPs with different lipid core, the MLCD NPs showed a lower macrophages cell uptake but higher B16 cell uptake, suggesting a longer circulation time in blood but higher cancer cell internalization. This work shed light on the interactions between MLCD NPs and proteins, which is significant for application as nanocarriers with improved biological efficacy. Elsevier 2024-11 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/115557/1/115557.pdf Chen, Canfeng and Alfredo, Ying Ye and Lee, Yee Ying and Tan, Chin Ping and Wang, Yong and Qiu, Chaoying (2024) Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona. International Journal of Biological Macromolecules, 281 (pt.1). art. no. 136223. pp. 1-14. ISSN 0141-8130; eISSN: 1879-0003 https://www.sciencedirect.com/science/article/pii/S0141813024070326?via%3Dihub 10.1016/j.ijbiomac.2024.136223
spellingShingle Chen, Canfeng
Alfredo, Ying Ye
Lee, Yee Ying
Tan, Chin Ping
Wang, Yong
Qiu, Chaoying
Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona
title Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona
title_full Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona
title_fullStr Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona
title_full_unstemmed Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona
title_short Physicochemical and biological characterization of the lipid particles with bovine serum albumin corona
title_sort physicochemical and biological characterization of the lipid particles with bovine serum albumin corona
url http://psasir.upm.edu.my/id/eprint/115557/
http://psasir.upm.edu.my/id/eprint/115557/
http://psasir.upm.edu.my/id/eprint/115557/
http://psasir.upm.edu.my/id/eprint/115557/1/115557.pdf