Rheological properties of isotactic polypropylene/kaolin composites

Rheological properties of isotactic polypropylene/kaolin composites have been evaluated at kaolin concentrations 0-17.4 vol% at 493K. The systems obeyed power-law model in shear stress-shear rate variations and were shear thinning, which increased with kaolin content. Apparent melt viscosity decreas...

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Bibliographic Details
Main Authors: Maiti, S.N., Lopez, B.H., Ibrahim, Mohd Nordin
Format: Article
Published: Informa UK Limited 2002
Online Access:http://psasir.upm.edu.my/id/eprint/115467/
Description
Summary:Rheological properties of isotactic polypropylene/kaolin composites have been evaluated at kaolin concentrations 0-17.4 vol% at 493K. The systems obeyed power-law model in shear stress-shear rate variations and were shear thinning, which increased with kaolin content. Apparent melt viscosity decreased up to 5% kaolin and increased with further increase in kaolin concentration. First normal stress difference increased up to 5 vol% kaolin and decreased beyond this kaolin content. Use of a titanate coupling agent modified the rheological properties through an enhanced bonding between the filler and the polymer.