Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide

The utilization of natural deep eutectic solvents in the extraction of lignin presents a promising sustainable approach for biorefineries. While lignin extracted with NADES has been utilized in various applications, there is a lack of research on its potential for CO2 adsorption. This article aims t...

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Main Authors: Meraj, Aatikah, Jawaid, M., Nasef, Mohamed Mahmoud, Mohamad, Noor Ashikin, Singh, Surendra Pratap, Ariffin, Hidayah, Abu‐Jdayil, Basim
Format: Article
Published: Springer Science and Business Media Deutschland GmbH 2024
Online Access:http://psasir.upm.edu.my/id/eprint/115266/
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author Meraj, Aatikah
Jawaid, M.
Nasef, Mohamed Mahmoud
Mohamad, Noor Ashikin
Singh, Surendra Pratap
Ariffin, Hidayah
Abu‐Jdayil, Basim
author_facet Meraj, Aatikah
Jawaid, M.
Nasef, Mohamed Mahmoud
Mohamad, Noor Ashikin
Singh, Surendra Pratap
Ariffin, Hidayah
Abu‐Jdayil, Basim
author_sort Meraj, Aatikah
building UPM Institutional Repository
collection Online Access
description The utilization of natural deep eutectic solvents in the extraction of lignin presents a promising sustainable approach for biorefineries. While lignin extracted with NADES has been utilized in various applications, there is a lack of research on its potential for CO2 adsorption. This article aims to assess the potential of CO2 adsorption on lignin extracted with NADES. In this work, lignin was studied, and their properties were analyzed using analytical techniques such as FTIR, XRD, TGA, SEM, BET, and particle size analysis. The gravimetric adsorption method was employed to evaluate the CO2 adsorption capacity of lignin. Thermal analysis showed broader decomposition at 416.45 °C, suggesting potential suitability for exploration of CO2 adsorption. The lignin exhibited high selectivity towards CO2 at an adsorption capacity of 75 mg/g at 30 bar. Lignin exhibited Type-II adsorption isotherm which indicates existence of multilayer adsorption. CO2 adsorption performance agrees well with BET and SEM results, revealing low surface area in the NADES extracted lignin and dense-like structure. It also showed good stability after 10 adsorption/desorption cycles. The overall results of this study suggests that the lignin extracted with NADES has the potential for application in CO2 adsorption that requires further exploration.
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spelling upm-1152662025-03-10T07:30:28Z http://psasir.upm.edu.my/id/eprint/115266/ Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide Meraj, Aatikah Jawaid, M. Nasef, Mohamed Mahmoud Mohamad, Noor Ashikin Singh, Surendra Pratap Ariffin, Hidayah Abu‐Jdayil, Basim The utilization of natural deep eutectic solvents in the extraction of lignin presents a promising sustainable approach for biorefineries. While lignin extracted with NADES has been utilized in various applications, there is a lack of research on its potential for CO2 adsorption. This article aims to assess the potential of CO2 adsorption on lignin extracted with NADES. In this work, lignin was studied, and their properties were analyzed using analytical techniques such as FTIR, XRD, TGA, SEM, BET, and particle size analysis. The gravimetric adsorption method was employed to evaluate the CO2 adsorption capacity of lignin. Thermal analysis showed broader decomposition at 416.45 °C, suggesting potential suitability for exploration of CO2 adsorption. The lignin exhibited high selectivity towards CO2 at an adsorption capacity of 75 mg/g at 30 bar. Lignin exhibited Type-II adsorption isotherm which indicates existence of multilayer adsorption. CO2 adsorption performance agrees well with BET and SEM results, revealing low surface area in the NADES extracted lignin and dense-like structure. It also showed good stability after 10 adsorption/desorption cycles. The overall results of this study suggests that the lignin extracted with NADES has the potential for application in CO2 adsorption that requires further exploration. Springer Science and Business Media Deutschland GmbH 2024-05-14 Article PeerReviewed Meraj, Aatikah and Jawaid, M. and Nasef, Mohamed Mahmoud and Mohamad, Noor Ashikin and Singh, Surendra Pratap and Ariffin, Hidayah and Abu‐Jdayil, Basim (2024) Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide. Biomass Conversion and Biorefinery. pp. 7323-7332. ISSN 2190-6815; eISSN: 2190-6823 https://link.springer.com/article/10.1007/s13399-024-05731-x?error=cookies_not_supported&code=a29186e9-8c7f-46f5-a82e-2f1d8e2dd44e 10.1007/s13399-024-05731-x
spellingShingle Meraj, Aatikah
Jawaid, M.
Nasef, Mohamed Mahmoud
Mohamad, Noor Ashikin
Singh, Surendra Pratap
Ariffin, Hidayah
Abu‐Jdayil, Basim
Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide
title Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide
title_full Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide
title_fullStr Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide
title_full_unstemmed Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide
title_short Exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide
title_sort exploring the potential of lignin extracted with natural deep eutectic solvents for adsorption of carbon dioxide
url http://psasir.upm.edu.my/id/eprint/115266/
http://psasir.upm.edu.my/id/eprint/115266/
http://psasir.upm.edu.my/id/eprint/115266/