Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate
The synthesis and room temperature structural characterization of the title compound [AgL2]+ (ClO4)-, L = 2, 6-diacetylpyridine, are reported. Crystals are orthorhombic, Pcan, a 19.629(7), b 14.603(4) and c 14.469(4) Å, Z = 8; R was 0.050 for 1987 'observed' reflections. The structure cont...
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| Format: | Article |
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CSIRO Publishing
1989
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| Online Access: | http://psasir.upm.edu.my/id/eprint/115193/ |
| _version_ | 1848866710957850624 |
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| author | Bin, Sidik Silong Engelhardt, Lutz M. White, Allan H. |
| author_facet | Bin, Sidik Silong Engelhardt, Lutz M. White, Allan H. |
| author_sort | Bin, Sidik Silong |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The synthesis and room temperature structural characterization of the title compound [AgL2]+ (ClO4)-, L = 2, 6-diacetylpyridine, are reported. Crystals are orthorhombic, Pcan, a 19.629(7), b 14.603(4) and c 14.469(4) Å, Z = 8; R was 0.050 for 1987 'observed' reflections. The structure contains two independent [AgL2]+ species, the central nitrogen atoms of the quasi-tridentate ligands being opposed in the coordination spheres of the silver atoms. Both have crystallographically imposed 2 symmetry; in one, this is normal to the N-Ag-N line [actual bond angle, 175.6(2)°; Ag-N, 2.316(6), Ag-O, 2.589(7) and 2.522(7) Å], relating the two ligands. In the other, it is coincident; for one ligand Ag-N and Ag-O are 2.285(8) and 2.500(8) Å, while for the other the two values are 2.271(8) and 2.543(7) Å. The silver-nitrogen distances are appreciably longer than the value of 2.166(4) Å found for the [Ag(py)2]+ cation. |
| first_indexed | 2025-11-15T14:24:56Z |
| format | Article |
| id | upm-115193 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T14:24:56Z |
| publishDate | 1989 |
| publisher | CSIRO Publishing |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1151932025-02-26T02:16:27Z http://psasir.upm.edu.my/id/eprint/115193/ Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate Bin, Sidik Silong Engelhardt, Lutz M. White, Allan H. The synthesis and room temperature structural characterization of the title compound [AgL2]+ (ClO4)-, L = 2, 6-diacetylpyridine, are reported. Crystals are orthorhombic, Pcan, a 19.629(7), b 14.603(4) and c 14.469(4) Å, Z = 8; R was 0.050 for 1987 'observed' reflections. The structure contains two independent [AgL2]+ species, the central nitrogen atoms of the quasi-tridentate ligands being opposed in the coordination spheres of the silver atoms. Both have crystallographically imposed 2 symmetry; in one, this is normal to the N-Ag-N line [actual bond angle, 175.6(2)°; Ag-N, 2.316(6), Ag-O, 2.589(7) and 2.522(7) Å], relating the two ligands. In the other, it is coincident; for one ligand Ag-N and Ag-O are 2.285(8) and 2.500(8) Å, while for the other the two values are 2.271(8) and 2.543(7) Å. The silver-nitrogen distances are appreciably longer than the value of 2.166(4) Å found for the [Ag(py)2]+ cation. CSIRO Publishing 1989 Article PeerReviewed Bin, Sidik Silong and Engelhardt, Lutz M. and White, Allan H. (1989) Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate. Australian Journal of Chemistry, 42 (8). pp. 1381-1386. ISSN 0004-9425; eISSN: 1445-0038 https://www.publish.csiro.au/ch/CH9891381 10.1071/CH9891381 |
| spellingShingle | Bin, Sidik Silong Engelhardt, Lutz M. White, Allan H. Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate |
| title | Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate |
| title_full | Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate |
| title_fullStr | Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate |
| title_full_unstemmed | Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate |
| title_short | Lewis-base adducts of group 11 metal(i) compounds. LVII. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate |
| title_sort | lewis-base adducts of group 11 metal(i) compounds. lvii. crystal structure of bis(2, 6-diacetyl-pyridine)silver(i) perchlorate |
| url | http://psasir.upm.edu.my/id/eprint/115193/ http://psasir.upm.edu.my/id/eprint/115193/ http://psasir.upm.edu.my/id/eprint/115193/ |