Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
This research addresses the significant challenges of waste disposal and the need for sustainable production in the ceramics industry by introducing an approach to fabricating calcium-alumino-silicate-fluoride (CASF) based glass ceramics. Using recyclable materials such as waste soda-lime-silicate (...
| Main Authors: | , , , , , , , |
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| Format: | Article |
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Springer
2024
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| Online Access: | http://psasir.upm.edu.my/id/eprint/114986/ |
| _version_ | 1848866653506371584 |
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| author | Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha |
| author_facet | Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha |
| author_sort | Roslan, Zuraidah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | This research addresses the significant challenges of waste disposal and the need for sustainable production in the ceramics industry by introducing an approach to fabricating calcium-alumino-silicate-fluoride (CASF) based glass ceramics. Using recyclable materials such as waste soda-lime-silicate (SLS) glass and clam shells (CS) as primary precursors, a controlled melt-quenching process was employed to investigate how varying the CaO/CaF2 ratios influences the physical and structural properties of CASF glass ceramics. The waste materials and CASF glass ceramics were analyzed using X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transforms infrared (FTIR), Scanning electron microscopy (SEM), and Energy dispersive X-ray (EDX) spectroscopy. XRD indicated the crystalline structure in all CASF glass ceramics samples while FTIR spectroscopy detected several linkages, including PO43−, Si-OH, Si-O-Si, CO2, and O-H indicating the development of CASF glass ceramics. SEM analysis showed a non-uniform distribution of particles and EDX analysis, shows the calcium-to-phosphate molar ratio (Ca/P) of CASF glass ceramics. The glass ceramics labeled as G6 possessed better properties, with a minor crystalline phase identified as fluorapatite (Ca5(PO4)3F), which is compatible with the commercial bioglass. These results demonstrate a cost-effective waste-derived bioglass system used in biomedical fields. |
| first_indexed | 2025-11-15T14:24:01Z |
| format | Article |
| id | upm-114986 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T14:24:01Z |
| publishDate | 2024 |
| publisher | Springer |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1149862025-02-13T08:00:43Z http://psasir.upm.edu.my/id/eprint/114986/ Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha This research addresses the significant challenges of waste disposal and the need for sustainable production in the ceramics industry by introducing an approach to fabricating calcium-alumino-silicate-fluoride (CASF) based glass ceramics. Using recyclable materials such as waste soda-lime-silicate (SLS) glass and clam shells (CS) as primary precursors, a controlled melt-quenching process was employed to investigate how varying the CaO/CaF2 ratios influences the physical and structural properties of CASF glass ceramics. The waste materials and CASF glass ceramics were analyzed using X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transforms infrared (FTIR), Scanning electron microscopy (SEM), and Energy dispersive X-ray (EDX) spectroscopy. XRD indicated the crystalline structure in all CASF glass ceramics samples while FTIR spectroscopy detected several linkages, including PO43−, Si-OH, Si-O-Si, CO2, and O-H indicating the development of CASF glass ceramics. SEM analysis showed a non-uniform distribution of particles and EDX analysis, shows the calcium-to-phosphate molar ratio (Ca/P) of CASF glass ceramics. The glass ceramics labeled as G6 possessed better properties, with a minor crystalline phase identified as fluorapatite (Ca5(PO4)3F), which is compatible with the commercial bioglass. These results demonstrate a cost-effective waste-derived bioglass system used in biomedical fields. Springer 2024-11-27 Article PeerReviewed Roslan, Zuraidah and Amin, Khamirul Matori and Mohd Zaid, Mohd Hafiz and Yaakob, Yazid and Kul, Esra and Loh, Zhi Wei and Zarzali Shah, Aishah and Ahmad Zahudi, Afrina Zulaikha (2024) Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials. Applied Physics A: Materials Science and Processing, 130 (12). art. no. 931. ISSN 0947-8396; eISSN: 1432-0630 https://link.springer.com/article/10.1007/s00339-024-08053-x?error=cookies_not_supported&code=9ac9985f-73d0-4d5b-9eef-0a4710d96eff 10.1007/s00339-024-08053-x |
| spellingShingle | Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials |
| title | Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials |
| title_full | Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials |
| title_fullStr | Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials |
| title_full_unstemmed | Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials |
| title_short | Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials |
| title_sort | investigating the influence of cao/caf2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials |
| url | http://psasir.upm.edu.my/id/eprint/114986/ http://psasir.upm.edu.my/id/eprint/114986/ http://psasir.upm.edu.my/id/eprint/114986/ |