Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.

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Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.

The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction.

Bibliographic Details
Main Authors:	Lajis, Nordin Hj., Khan, Mohammad Niyaz
Format:	Article
Published:	Elsevier 1992
Online Access:	http://psasir.upm.edu.my/id/eprint/114121/

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