Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction.
| Main Authors: | , |
|---|---|
| Format: | Article |
| Published: |
Elsevier
1992
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/114121/ |
| _version_ | 1848866411008491520 |
|---|---|
| author | Lajis, Nordin Hj. Khan, Mohammad Niyaz |
| author_facet | Lajis, Nordin Hj. Khan, Mohammad Niyaz |
| author_sort | Lajis, Nordin Hj. |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction. |
| first_indexed | 2025-11-15T14:20:10Z |
| format | Article |
| id | upm-114121 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T14:20:10Z |
| publishDate | 1992 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1141212024-12-03T04:03:03Z http://psasir.upm.edu.my/id/eprint/114121/ Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. Lajis, Nordin Hj. Khan, Mohammad Niyaz The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction. Elsevier 1992-05 Article PeerReviewed Lajis, Nordin Hj. and Khan, Mohammad Niyaz (1992) Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. Tetrahedron, 48 (6). pp. 1109-1114. ISSN 0040-4020; eISSN: 0040-4020 https://linkinghub.elsevier.com/retrieve/pii/S0040402001882065 10.1016/s0040-4020(01)88206-5 |
| spellingShingle | Lajis, Nordin Hj. Khan, Mohammad Niyaz Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. |
| title | Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. |
| title_full | Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. |
| title_fullStr | Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. |
| title_full_unstemmed | Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. |
| title_short | Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. |
| title_sort | solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. |
| url | http://psasir.upm.edu.my/id/eprint/114121/ http://psasir.upm.edu.my/id/eprint/114121/ http://psasir.upm.edu.my/id/eprint/114121/ |