Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio
The catalytic conversion of Reutealis trisperma oil was carried out over a Al-MCM-41 based catalyst with different Si/Al ratio with no added hydrogen to examine the possibility of the direct production of hydrocarbons in the ranges of jet fuel. In a semi-batch reactor, RTO was combined with 3 % cata...
| Main Authors: | , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2024
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| Online Access: | http://psasir.upm.edu.my/id/eprint/113741/ http://psasir.upm.edu.my/id/eprint/113741/1/113741.pdf |
| _version_ | 1848866309709758464 |
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| author | Nugraha, Reva Edra Prasetyoko, Didik Nareswari, Nabila Argya Aziz, Abdul Holilah, Holilah Bahruji, Hasliza Yusop, Muhammad Rahimi Asikin-Mijan, Nurul Suprapto, Suprapto Taufiq-Yap, Yun Hin Abdul Jalil, Aishah Purnami, Santi Wulan Hartati, Hartati |
| author_facet | Nugraha, Reva Edra Prasetyoko, Didik Nareswari, Nabila Argya Aziz, Abdul Holilah, Holilah Bahruji, Hasliza Yusop, Muhammad Rahimi Asikin-Mijan, Nurul Suprapto, Suprapto Taufiq-Yap, Yun Hin Abdul Jalil, Aishah Purnami, Santi Wulan Hartati, Hartati |
| author_sort | Nugraha, Reva Edra |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The catalytic conversion of Reutealis trisperma oil was carried out over a Al-MCM-41 based catalyst with different Si/Al ratio with no added hydrogen to examine the possibility of the direct production of hydrocarbons in the ranges of jet fuel. In a semi-batch reactor, RTO was combined with 3 % catalyst and heated to 350 °C for 4h. The blank reaction shows the lowest conversion and liquid yield, with values of 39.65 % and 8.74 %, respectively. In contrast, the highest conversion was achieved using the Al-MCM-41 (30) catalyst, and the conversion decreases as the Si/Al ratio of the Al-MCM-41 catalyst increases. Indeed, the mesoporous structure enabled extensive bio-oil diffusion and adsorption, further increasing catalytic conversion. The Al-MCM-41 (30) shows the great performance in catalytic conversion of RTO to hydrocarbon and aromatic chain hydrocarbon. The Al-MCM-41 (30) catalyst resulted in a composition of 41.26 % paraffin, 6.78 % olefin, 21.77 % arenes, and 11.44 % cycloparaffin. This composition is comparable to JP-8 and Jet-A fuels, satisfying the ASTM D7566 standard for aircraft turbine fuel containing synthetic hydrocarbons. The acid site and pore size on the support material influenced the interaction of bio-oil molecules and catalyst which increasing the rate of reactant/product diffusion and improve the jet-fuel production. The obtained results are promising for the use of non-edible RTO and kaolin-derived catalysts in the production of sustainable alternative jet fuels. This approach offers competitive costs and significant environmental and social benefits. © 2024 The Authors |
| first_indexed | 2025-11-15T14:18:33Z |
| format | Article |
| id | upm-113741 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T14:18:33Z |
| publishDate | 2024 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1137412025-01-15T03:36:51Z http://psasir.upm.edu.my/id/eprint/113741/ Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio Nugraha, Reva Edra Prasetyoko, Didik Nareswari, Nabila Argya Aziz, Abdul Holilah, Holilah Bahruji, Hasliza Yusop, Muhammad Rahimi Asikin-Mijan, Nurul Suprapto, Suprapto Taufiq-Yap, Yun Hin Abdul Jalil, Aishah Purnami, Santi Wulan Hartati, Hartati The catalytic conversion of Reutealis trisperma oil was carried out over a Al-MCM-41 based catalyst with different Si/Al ratio with no added hydrogen to examine the possibility of the direct production of hydrocarbons in the ranges of jet fuel. In a semi-batch reactor, RTO was combined with 3 % catalyst and heated to 350 °C for 4h. The blank reaction shows the lowest conversion and liquid yield, with values of 39.65 % and 8.74 %, respectively. In contrast, the highest conversion was achieved using the Al-MCM-41 (30) catalyst, and the conversion decreases as the Si/Al ratio of the Al-MCM-41 catalyst increases. Indeed, the mesoporous structure enabled extensive bio-oil diffusion and adsorption, further increasing catalytic conversion. The Al-MCM-41 (30) shows the great performance in catalytic conversion of RTO to hydrocarbon and aromatic chain hydrocarbon. The Al-MCM-41 (30) catalyst resulted in a composition of 41.26 % paraffin, 6.78 % olefin, 21.77 % arenes, and 11.44 % cycloparaffin. This composition is comparable to JP-8 and Jet-A fuels, satisfying the ASTM D7566 standard for aircraft turbine fuel containing synthetic hydrocarbons. The acid site and pore size on the support material influenced the interaction of bio-oil molecules and catalyst which increasing the rate of reactant/product diffusion and improve the jet-fuel production. The obtained results are promising for the use of non-edible RTO and kaolin-derived catalysts in the production of sustainable alternative jet fuels. This approach offers competitive costs and significant environmental and social benefits. © 2024 The Authors Elsevier 2024 Article PeerReviewed text en cc_by_nc_4 http://psasir.upm.edu.my/id/eprint/113741/1/113741.pdf Nugraha, Reva Edra and Prasetyoko, Didik and Nareswari, Nabila Argya and Aziz, Abdul and Holilah, Holilah and Bahruji, Hasliza and Yusop, Muhammad Rahimi and Asikin-Mijan, Nurul and Suprapto, Suprapto and Taufiq-Yap, Yun Hin and Abdul Jalil, Aishah and Purnami, Santi Wulan and Hartati, Hartati (2024) Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio. Case Studies in Chemical and Environmental Engineering, 10. art. no. 100877. pp. 1-11. ISSN 2666-0164; eISSN: 2666-0164 https://linkinghub.elsevier.com/retrieve/pii/S2666016424002718 10.1016/j.cscee.2024.100877 |
| spellingShingle | Nugraha, Reva Edra Prasetyoko, Didik Nareswari, Nabila Argya Aziz, Abdul Holilah, Holilah Bahruji, Hasliza Yusop, Muhammad Rahimi Asikin-Mijan, Nurul Suprapto, Suprapto Taufiq-Yap, Yun Hin Abdul Jalil, Aishah Purnami, Santi Wulan Hartati, Hartati Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio |
| title | Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio |
| title_full | Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio |
| title_fullStr | Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio |
| title_full_unstemmed | Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio |
| title_short | Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio |
| title_sort | jet-fuel range hydrocarbon production from reutealis trisperma oil over al-mcm-41 derived from indonesian kaolin with different si/a1 ratio |
| url | http://psasir.upm.edu.my/id/eprint/113741/ http://psasir.upm.edu.my/id/eprint/113741/ http://psasir.upm.edu.my/id/eprint/113741/ http://psasir.upm.edu.my/id/eprint/113741/1/113741.pdf |