Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system

Bioactive glasses containing boron oxide have attracted substantial attention owing to their unique attributes and the promising prospects they offer for biomedical uses. The study explores boro calcium fluoro alumino silicate (BCFAS) glass containing boron oxide, highlighting its potential in biome...

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Main Authors: Mohammed Efa, Abdelkader, Matori, Khamirul Amin, Mohd Zaid, Mohd Hafiz, Che Abdullah, Che Azurahanim, Zainuddin, Norhazlin, Mayzan, Mohd Zul Hilmi, Kamis, Shahira Liza
Format: Article
Published: Springer Science and Business Media 2024
Online Access:http://psasir.upm.edu.my/id/eprint/113720/
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author Mohammed Efa, Abdelkader
Matori, Khamirul Amin
Mohd Zaid, Mohd Hafiz
Che Abdullah, Che Azurahanim
Zainuddin, Norhazlin
Mayzan, Mohd Zul Hilmi
Kamis, Shahira Liza
author_facet Mohammed Efa, Abdelkader
Matori, Khamirul Amin
Mohd Zaid, Mohd Hafiz
Che Abdullah, Che Azurahanim
Zainuddin, Norhazlin
Mayzan, Mohd Zul Hilmi
Kamis, Shahira Liza
author_sort Mohammed Efa, Abdelkader
building UPM Institutional Repository
collection Online Access
description Bioactive glasses containing boron oxide have attracted substantial attention owing to their unique attributes and the promising prospects they offer for biomedical uses. The study explores boro calcium fluoro alumino silicate (BCFAS) glass containing boron oxide, highlighting its potential in biomedical applications. The glass was synthesized through melt-water quenching with varying B2O3 ratios, utilizing CaO from clam shell and SiO2 from soda lime silica glass waste. The investigation examined the physical and mechanical properties of the resulting samples. Results showed that increasing B2O3 content caused a reduction in crystallinity, as confirmed by XRD analysis. The incorporation of B2O3 into the glass structure was further supported by the emergence of B‒O‒B and Si‒O‒B bonds observed in FTIR spectroscopy, which may potentially influence the glass's dissolution and degradation characteristics. However, higher B2O3 content also reduced density, impacting the mechanical properties. Vickers microhardness and compressive strength decreased due to the introduction of the BO3 unit, which increased the fragility of the glass. While enhancing glass-like behavior and potentially increasing bioactivity, the addition of B2O3 adversely affected its mechanical attributes. © The Author(s), under exclusive licence to Springer Nature B.V. 2024.
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spelling upm-1137202025-01-17T09:00:00Z http://psasir.upm.edu.my/id/eprint/113720/ Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system Mohammed Efa, Abdelkader Matori, Khamirul Amin Mohd Zaid, Mohd Hafiz Che Abdullah, Che Azurahanim Zainuddin, Norhazlin Mayzan, Mohd Zul Hilmi Kamis, Shahira Liza Bioactive glasses containing boron oxide have attracted substantial attention owing to their unique attributes and the promising prospects they offer for biomedical uses. The study explores boro calcium fluoro alumino silicate (BCFAS) glass containing boron oxide, highlighting its potential in biomedical applications. The glass was synthesized through melt-water quenching with varying B2O3 ratios, utilizing CaO from clam shell and SiO2 from soda lime silica glass waste. The investigation examined the physical and mechanical properties of the resulting samples. Results showed that increasing B2O3 content caused a reduction in crystallinity, as confirmed by XRD analysis. The incorporation of B2O3 into the glass structure was further supported by the emergence of B‒O‒B and Si‒O‒B bonds observed in FTIR spectroscopy, which may potentially influence the glass's dissolution and degradation characteristics. However, higher B2O3 content also reduced density, impacting the mechanical properties. Vickers microhardness and compressive strength decreased due to the introduction of the BO3 unit, which increased the fragility of the glass. While enhancing glass-like behavior and potentially increasing bioactivity, the addition of B2O3 adversely affected its mechanical attributes. © The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Science and Business Media 2024 Article PeerReviewed Mohammed Efa, Abdelkader and Matori, Khamirul Amin and Mohd Zaid, Mohd Hafiz and Che Abdullah, Che Azurahanim and Zainuddin, Norhazlin and Mayzan, Mohd Zul Hilmi and Kamis, Shahira Liza (2024) Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system. Silicon, 16 (13-14). pp. 5327-5336. ISSN 1876-990X; eISSN: 1876-9918 https://link.springer.com/article/10.1007/s12633-024-03072-y?error=cookies_not_supported&code=d668a97c-17f7-4e2f-9aba-a8b76df32053 10.1007/s12633-024-03072-y
spellingShingle Mohammed Efa, Abdelkader
Matori, Khamirul Amin
Mohd Zaid, Mohd Hafiz
Che Abdullah, Che Azurahanim
Zainuddin, Norhazlin
Mayzan, Mohd Zul Hilmi
Kamis, Shahira Liza
Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system
title Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system
title_full Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system
title_fullStr Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system
title_full_unstemmed Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system
title_short Effect of B2O3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system
title_sort effect of b2o3 on the physical and mechanical properties of calcium fluoroaluminosilicate glass system
url http://psasir.upm.edu.my/id/eprint/113720/
http://psasir.upm.edu.my/id/eprint/113720/
http://psasir.upm.edu.my/id/eprint/113720/