Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites

In this study, significant improvements in mechanical properties have been seen through the efficient inclusion of Oil Palm Cellulose Nanofibrils (CNF) as nano-fillers into green polymer matrices produced from biomass with a 28 % carbon content. The goal of the research was to make green epoxy nanoc...

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Main Authors: Yusuf, J., Salit @ Sinon, Mohd Sapuan, Rashid, Umer, Ilyas, R.A., Hassan, M.R.
Format: Article
Language:English
Published: Elsevier 2024
Online Access:http://psasir.upm.edu.my/id/eprint/113301/
http://psasir.upm.edu.my/id/eprint/113301/1/113301.pdf
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author Yusuf, J.
Salit @ Sinon, Mohd Sapuan
Rashid, Umer
Ilyas, R.A.
Hassan, M.R.
author_facet Yusuf, J.
Salit @ Sinon, Mohd Sapuan
Rashid, Umer
Ilyas, R.A.
Hassan, M.R.
author_sort Yusuf, J.
building UPM Institutional Repository
collection Online Access
description In this study, significant improvements in mechanical properties have been seen through the efficient inclusion of Oil Palm Cellulose Nanofibrils (CNF) as nano-fillers into green polymer matrices produced from biomass with a 28 % carbon content. The goal of the research was to make green epoxy nanocomposites utilizing solution blending process with acetone as the solvent with the different CNF loadings (0.1, 0.25, and 0.5 wt%). An ultrasonic bath was used in conjunction with mechanical stirring to guarantee that CNF was effectively dispersed throughout the green epoxy. The resultant nanocomposites underwent thorough evaluation, comparing them to unfilled green epoxy and evaluating their morphological, mechanical, and thermal behavior using a variety of instruments. Field-emission scanning electron microscopy (FE-SEM) was used to validate findings, which showed that the CNF were dispersed optimally inside the nanocomposites. The thermal degradation temperature (Td) of the nanocomposites showed a marginal decrement of 0.8 % in temperatures (from 348 °C to 345 °C), between unfilled green epoxy (neat) and 0.1 wt% of CNF loading. The mechanical test results, which showed a 13.3 % improvement in hardness and a 6.45 % rise in tensile strength when compared to unfilled green epoxy, were in line with previously published research. Overall, the outcomes showed that green nanocomposites have significantly improved in performance. © 2024 Elsevier B.V.
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spelling upm-1133012024-11-18T05:00:36Z http://psasir.upm.edu.my/id/eprint/113301/ Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites Yusuf, J. Salit @ Sinon, Mohd Sapuan Rashid, Umer Ilyas, R.A. Hassan, M.R. In this study, significant improvements in mechanical properties have been seen through the efficient inclusion of Oil Palm Cellulose Nanofibrils (CNF) as nano-fillers into green polymer matrices produced from biomass with a 28 % carbon content. The goal of the research was to make green epoxy nanocomposites utilizing solution blending process with acetone as the solvent with the different CNF loadings (0.1, 0.25, and 0.5 wt%). An ultrasonic bath was used in conjunction with mechanical stirring to guarantee that CNF was effectively dispersed throughout the green epoxy. The resultant nanocomposites underwent thorough evaluation, comparing them to unfilled green epoxy and evaluating their morphological, mechanical, and thermal behavior using a variety of instruments. Field-emission scanning electron microscopy (FE-SEM) was used to validate findings, which showed that the CNF were dispersed optimally inside the nanocomposites. The thermal degradation temperature (Td) of the nanocomposites showed a marginal decrement of 0.8 % in temperatures (from 348 °C to 345 °C), between unfilled green epoxy (neat) and 0.1 wt% of CNF loading. The mechanical test results, which showed a 13.3 % improvement in hardness and a 6.45 % rise in tensile strength when compared to unfilled green epoxy, were in line with previously published research. Overall, the outcomes showed that green nanocomposites have significantly improved in performance. © 2024 Elsevier B.V. Elsevier 2024 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/113301/1/113301.pdf Yusuf, J. and Salit @ Sinon, Mohd Sapuan and Rashid, Umer and Ilyas, R.A. and Hassan, M.R. (2024) Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites. International Journal of Biological Macromolecules, 278 (pt.3). art. no. 134421. pp. 1-9. ISSN 0141-8130; eISSN: 1879-0003 https://www.sciencedirect.com/science/article/pii/S0141813024052267?via%3Dihub 10.1016/j.ijbiomac.2024.134421
spellingShingle Yusuf, J.
Salit @ Sinon, Mohd Sapuan
Rashid, Umer
Ilyas, R.A.
Hassan, M.R.
Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites
title Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites
title_full Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites
title_fullStr Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites
title_full_unstemmed Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites
title_short Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites
title_sort thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites
url http://psasir.upm.edu.my/id/eprint/113301/
http://psasir.upm.edu.my/id/eprint/113301/
http://psasir.upm.edu.my/id/eprint/113301/
http://psasir.upm.edu.my/id/eprint/113301/1/113301.pdf