Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
Stationary energy storage infrastructure based on zinc-ion transport and storage chemistry is attracting more attention due to favorable metrics, including cost, safety, and recycling feasibility. However, splitting water and liquid electrolyte fluidity lead to cathode dissolution and Zn corrosion,...
| Main Authors: | , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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American Chemical Society
2024
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| Online Access: | http://psasir.upm.edu.my/id/eprint/113267/ http://psasir.upm.edu.my/id/eprint/113267/1/113267.pdf |
| _version_ | 1848866176036241408 |
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| author | Meng, Xiangxuan Du, Mingdong Li, Yuning Du, Shiji Zhao, Lixin Zheng, Shunri Zhang, Jian Li, Haibo Qiao, Liang Tan, Kar Ban Han, Wenjuan Xu, Shichong Li, Jiaming Lu, Ming |
| author_facet | Meng, Xiangxuan Du, Mingdong Li, Yuning Du, Shiji Zhao, Lixin Zheng, Shunri Zhang, Jian Li, Haibo Qiao, Liang Tan, Kar Ban Han, Wenjuan Xu, Shichong Li, Jiaming Lu, Ming |
| author_sort | Meng, Xiangxuan |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Stationary energy storage infrastructure based on zinc-ion transport and storage chemistry is attracting more attention due to favorable metrics, including cost, safety, and recycling feasibility. However, splitting water and liquid electrolyte
fluidity lead to cathode dissolution and Zn corrosion, resulting in rapid attenuation of the capacity and service life. Herein, a new architecture of solid-state electrolytes with
high zinc ionic conductivity at room temperature was prepared via solidification of deep eutectic solvents utilizing MXene as nucleation additives. The ionic conductivity of MXene/ZCEs reached 6.69 × 10−4 S cm−1 at room temperature. Dendrite-free Zn plating/stripping with high reversibility can remain for over 2500 h. Subsequently, the fabricated solid-state zinc-ion battery with eliminated HER and suppressed Zn dendrites exhibited excellent cycling performance and could work normally in a range from −10 to 60 °C. This design inspired by eutectic solidification affords new insights into the multivalent solid electrochemistry suffering from slow ion migration. |
| first_indexed | 2025-11-15T14:16:26Z |
| format | Article |
| id | upm-113267 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T14:16:26Z |
| publishDate | 2024 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1132672024-11-20T05:44:49Z http://psasir.upm.edu.my/id/eprint/113267/ Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport Meng, Xiangxuan Du, Mingdong Li, Yuning Du, Shiji Zhao, Lixin Zheng, Shunri Zhang, Jian Li, Haibo Qiao, Liang Tan, Kar Ban Han, Wenjuan Xu, Shichong Li, Jiaming Lu, Ming Stationary energy storage infrastructure based on zinc-ion transport and storage chemistry is attracting more attention due to favorable metrics, including cost, safety, and recycling feasibility. However, splitting water and liquid electrolyte fluidity lead to cathode dissolution and Zn corrosion, resulting in rapid attenuation of the capacity and service life. Herein, a new architecture of solid-state electrolytes with high zinc ionic conductivity at room temperature was prepared via solidification of deep eutectic solvents utilizing MXene as nucleation additives. The ionic conductivity of MXene/ZCEs reached 6.69 × 10−4 S cm−1 at room temperature. Dendrite-free Zn plating/stripping with high reversibility can remain for over 2500 h. Subsequently, the fabricated solid-state zinc-ion battery with eliminated HER and suppressed Zn dendrites exhibited excellent cycling performance and could work normally in a range from −10 to 60 °C. This design inspired by eutectic solidification affords new insights into the multivalent solid electrochemistry suffering from slow ion migration. American Chemical Society 2024 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/113267/1/113267.pdf Meng, Xiangxuan and Du, Mingdong and Li, Yuning and Du, Shiji and Zhao, Lixin and Zheng, Shunri and Zhang, Jian and Li, Haibo and Qiao, Liang and Tan, Kar Ban and Han, Wenjuan and Xu, Shichong and Li, Jiaming and Lu, Ming (2024) Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport. Nano Letters, 24 (29). pp. 8818-8825. ISSN 1530-6984; eISSN: 1530-6992 https://pubs.acs.org/doi/abs/10.1021/acs.nanolett.4c01085 10.1021/acs.nanolett.4c01085 |
| spellingShingle | Meng, Xiangxuan Du, Mingdong Li, Yuning Du, Shiji Zhao, Lixin Zheng, Shunri Zhang, Jian Li, Haibo Qiao, Liang Tan, Kar Ban Han, Wenjuan Xu, Shichong Li, Jiaming Lu, Ming Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport |
| title | Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport |
| title_full | Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport |
| title_fullStr | Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport |
| title_full_unstemmed | Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport |
| title_short | Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport |
| title_sort | solidify eutectic electrolytes via the added mxene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport |
| url | http://psasir.upm.edu.my/id/eprint/113267/ http://psasir.upm.edu.my/id/eprint/113267/ http://psasir.upm.edu.my/id/eprint/113267/ http://psasir.upm.edu.my/id/eprint/113267/1/113267.pdf |