The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption

Activated carbon was impregnated with different concentrations of SnCl2.2H2O. Unimpregnated and impregnated activated carbons were analysed by means of physical adsorption and XPS and were tested for CO gas adsorption in a PSA system. The adsorption isotherms of N2 at 77 K were measured and showed a...

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Main Authors: Al-Khatib, Ma’an.F, Iyuke, Sunny E, Mohamad, Abu Bakar, Daud, Wan R.W, H Kadhum, Abdul Amir, M Shariff, Azmi, Yarmo, Mohd A
Format: Article
Language:English
Published: Elsevier 2002
Online Access:http://psasir.upm.edu.my/id/eprint/112987/
http://psasir.upm.edu.my/id/eprint/112987/1/112987.pdf
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author Al-Khatib, Ma’an.F
Iyuke, Sunny E
Mohamad, Abu Bakar
Daud, Wan R.W
H Kadhum, Abdul Amir
M Shariff, Azmi
Yarmo, Mohd A
author_facet Al-Khatib, Ma’an.F
Iyuke, Sunny E
Mohamad, Abu Bakar
Daud, Wan R.W
H Kadhum, Abdul Amir
M Shariff, Azmi
Yarmo, Mohd A
author_sort Al-Khatib, Ma’an.F
building UPM Institutional Repository
collection Online Access
description Activated carbon was impregnated with different concentrations of SnCl2.2H2O. Unimpregnated and impregnated activated carbons were analysed by means of physical adsorption and XPS and were tested for CO gas adsorption in a PSA system. The adsorption isotherms of N2 at 77 K were measured and showed a Type I isotherm indicating microporous carbon for all the samples. The surface area, pore volume and pore size distribution were reduced with impregnation. XPS analysis showed an increase in the intensity of Sn3d peak with impregnation. The impregnated activated carbon showed a very good adsorption ability of CO gas compared to the unimpregnated sample. The adsorptive species responsible for CO gas adsorption was confirmed to be SnO2 instead of SnO due to the former's comparative thermodynamic stability.
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institution Universiti Putra Malaysia
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publishDate 2002
publisher Elsevier
recordtype eprints
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spelling upm-1129872025-01-15T06:13:27Z http://psasir.upm.edu.my/id/eprint/112987/ The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption Al-Khatib, Ma’an.F Iyuke, Sunny E Mohamad, Abu Bakar Daud, Wan R.W H Kadhum, Abdul Amir M Shariff, Azmi Yarmo, Mohd A Activated carbon was impregnated with different concentrations of SnCl2.2H2O. Unimpregnated and impregnated activated carbons were analysed by means of physical adsorption and XPS and were tested for CO gas adsorption in a PSA system. The adsorption isotherms of N2 at 77 K were measured and showed a Type I isotherm indicating microporous carbon for all the samples. The surface area, pore volume and pore size distribution were reduced with impregnation. XPS analysis showed an increase in the intensity of Sn3d peak with impregnation. The impregnated activated carbon showed a very good adsorption ability of CO gas compared to the unimpregnated sample. The adsorptive species responsible for CO gas adsorption was confirmed to be SnO2 instead of SnO due to the former's comparative thermodynamic stability. Elsevier 2002 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/112987/1/112987.pdf Al-Khatib, Ma’an.F and Iyuke, Sunny E and Mohamad, Abu Bakar and Daud, Wan R.W and H Kadhum, Abdul Amir and M Shariff, Azmi and Yarmo, Mohd A (2002) The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption. Carbon, 40 (11). pp. 1929-1936. ISSN 0008-6223 https://linkinghub.elsevier.com/retrieve/pii/S000862230200026X 10.1016/s0008-6223(02)00026-x
spellingShingle Al-Khatib, Ma’an.F
Iyuke, Sunny E
Mohamad, Abu Bakar
Daud, Wan R.W
H Kadhum, Abdul Amir
M Shariff, Azmi
Yarmo, Mohd A
The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption
title The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption
title_full The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption
title_fullStr The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption
title_full_unstemmed The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption
title_short The effect of impregnation of activated carbon with SnCl2.2H2O on its porosity, surface composition and CO gas adsorption
title_sort effect of impregnation of activated carbon with sncl2.2h2o on its porosity, surface composition and co gas adsorption
url http://psasir.upm.edu.my/id/eprint/112987/
http://psasir.upm.edu.my/id/eprint/112987/
http://psasir.upm.edu.my/id/eprint/112987/
http://psasir.upm.edu.my/id/eprint/112987/1/112987.pdf