Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis
Dispersive micro solid phase extraction (D-μ-SPE) method using Graphene Oxide (GO) for the extraction and pre-concentration of selected polycyclic aromatic hydrocarbons (PAHs) from beverage samples prior to high-performance liquid chromatography - diode array detector (HPLC - DAD) is reported. Selec...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Akademi Sains Malaysia
2024
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| Online Access: | http://psasir.upm.edu.my/id/eprint/112821/ http://psasir.upm.edu.my/id/eprint/112821/1/112821.pdf |
| _version_ | 1848866046731091968 |
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| author | Anis, Ahmad Lutfi Kamaruzaman, Sazlinda Kamaruzaman, Sazlinda Zaini, Nurzaimah Mohammad Anwar, Farahnaz Wan Ibrahim, Wan Nazihah Mohamad Hanapi, Nor Suhaila |
| author_facet | Anis, Ahmad Lutfi Kamaruzaman, Sazlinda Kamaruzaman, Sazlinda Zaini, Nurzaimah Mohammad Anwar, Farahnaz Wan Ibrahim, Wan Nazihah Mohamad Hanapi, Nor Suhaila |
| author_sort | Anis, Ahmad Lutfi |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Dispersive micro solid phase extraction (D-μ-SPE) method using Graphene Oxide (GO) for the extraction and pre-concentration of selected polycyclic aromatic hydrocarbons (PAHs) from beverage samples prior to high-performance liquid chromatography - diode array detector (HPLC - DAD) is reported. Selected PAHs Fluorene (FLU) and Phenanthrene (PHE) were used as targeted analytes. An experimental design using Response Surface Methodology (RSM) and Box–Box–Behnken design (BBD) was performed to evaluate the interactive effects of three significant parameters: mass of sorbent, sample volume and extraction time. Under the optimum conditions, the method revealed good linearity (R2 = 0.9995 – 0.9998) over a concentration range of 0.5 – 5.0 mg L-1. The limit of detection (LOD) was in the range of 0.03 – 0.24 mg L-1 with satisfactory relative recoveries (81 – 99 %) and good relative standard deviation (RSD) of ≤ 3.80 % (n = 3). The method was successfully applied to tea, coffee, and milk samples and proved to be a simple, rapid, and reliable method with good extraction efficiencies for the detection of PAHs in beverage samples. © (2024), (Akademi Sains Malaysia). All Rights Reserved. |
| first_indexed | 2025-11-15T14:14:23Z |
| format | Article |
| id | upm-112821 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T14:14:23Z |
| publishDate | 2024 |
| publisher | Akademi Sains Malaysia |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1128212024-11-07T03:07:24Z http://psasir.upm.edu.my/id/eprint/112821/ Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis Anis, Ahmad Lutfi Kamaruzaman, Sazlinda Kamaruzaman, Sazlinda Zaini, Nurzaimah Mohammad Anwar, Farahnaz Wan Ibrahim, Wan Nazihah Mohamad Hanapi, Nor Suhaila Dispersive micro solid phase extraction (D-μ-SPE) method using Graphene Oxide (GO) for the extraction and pre-concentration of selected polycyclic aromatic hydrocarbons (PAHs) from beverage samples prior to high-performance liquid chromatography - diode array detector (HPLC - DAD) is reported. Selected PAHs Fluorene (FLU) and Phenanthrene (PHE) were used as targeted analytes. An experimental design using Response Surface Methodology (RSM) and Box–Box–Behnken design (BBD) was performed to evaluate the interactive effects of three significant parameters: mass of sorbent, sample volume and extraction time. Under the optimum conditions, the method revealed good linearity (R2 = 0.9995 – 0.9998) over a concentration range of 0.5 – 5.0 mg L-1. The limit of detection (LOD) was in the range of 0.03 – 0.24 mg L-1 with satisfactory relative recoveries (81 – 99 %) and good relative standard deviation (RSD) of ≤ 3.80 % (n = 3). The method was successfully applied to tea, coffee, and milk samples and proved to be a simple, rapid, and reliable method with good extraction efficiencies for the detection of PAHs in beverage samples. © (2024), (Akademi Sains Malaysia). All Rights Reserved. Akademi Sains Malaysia 2024 Article PeerReviewed text en cc_by_4 http://psasir.upm.edu.my/id/eprint/112821/1/112821.pdf Anis, Ahmad Lutfi and Kamaruzaman, Sazlinda and Kamaruzaman, Sazlinda and Zaini, Nurzaimah and Mohammad Anwar, Farahnaz and Wan Ibrahim, Wan Nazihah and Mohamad Hanapi, Nor Suhaila (2024) Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis. ASM Science Journal, 19. pp. 1-10. ISSN 1823-6782 https://www.akademisains.gov.my/asmsj/article/trace-determination-of-phenanthrene-and-fluorene-in-beverages-using-d-u-spe-and-liquid-chromatography-analysis/ 10.32802/asmscj.2023.1512 |
| spellingShingle | Anis, Ahmad Lutfi Kamaruzaman, Sazlinda Kamaruzaman, Sazlinda Zaini, Nurzaimah Mohammad Anwar, Farahnaz Wan Ibrahim, Wan Nazihah Mohamad Hanapi, Nor Suhaila Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis |
| title | Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis |
| title_full | Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis |
| title_fullStr | Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis |
| title_full_unstemmed | Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis |
| title_short | Trace determination of phenanthrene and fluorene in beverages using D-μ-SPE and liquid chromatography analysis |
| title_sort | trace determination of phenanthrene and fluorene in beverages using d-μ-spe and liquid chromatography analysis |
| url | http://psasir.upm.edu.my/id/eprint/112821/ http://psasir.upm.edu.my/id/eprint/112821/ http://psasir.upm.edu.my/id/eprint/112821/ http://psasir.upm.edu.my/id/eprint/112821/1/112821.pdf |