Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia

A transesterified experimental solid frying shortening was prepared from a palm stearin/palm kernel olein blend at 1:1 ratio (by weight) by using Rhizomucor miehei lipase at 60°C for 6 h. The fatty acid (FA) and triacylglycerol compositions, polymorphic forms, melting and cooling characteristics, sl...

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Main Authors: Chu, B. S., Ghazali, H. M., Lai, O. M., Che Man, Y. B., Yusof, S., Tee, S. B., Yusoff, M. S. A.
Format: Article
Language:English
Published: Wiley 2001
Online Access:http://psasir.upm.edu.my/id/eprint/112635/
http://psasir.upm.edu.my/id/eprint/112635/3/112635.pdf
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author Chu, B. S.
Ghazali, H. M.
Lai, O. M.
Che Man, Y. B.
Yusof, S.
Tee, S. B.
Yusoff, M. S. A.
author_facet Chu, B. S.
Ghazali, H. M.
Lai, O. M.
Che Man, Y. B.
Yusof, S.
Tee, S. B.
Yusoff, M. S. A.
author_sort Chu, B. S.
building UPM Institutional Repository
collection Online Access
description A transesterified experimental solid frying shortening was prepared from a palm stearin/palm kernel olein blend at 1:1 ratio (by weight) by using Rhizomucor miehei lipase at 60°C for 6 h. The fatty acid (FA) and triacylglycerol compositions, polymorphic forms, melting and cooling characteristics, slip melting point (SMP), and solid fat content (SFC) of the transesterified blend were then compared with five commercial solid frying shortenings (three domestic and two imported) found in Malaysia. All the domestic shortenings contained nonhydrogenated palm oil or palm olein and palm stearin as the hard stock, whereas the imported frying shortenings were formulated from soybean oil and cottonseed oil and contained high levels of β′ crystals. Trans FA were also found in these samples. The lipase-transesterified blend was found to be more β′-tending than the domestic samples. The SMP of the transesterified blend (47.0°C) fell within the range of the domestic samples (37.8-49.7°C) but was higher than the imported ones (42.3-43.0°C). All samples exhibited similar differential scanning calorimetry cooling profiles, with a narrow peak at the higher temperatures and a broad peak at the lower temperatures, even though their heating thermograms were quite different. Imported samples had flatter SFC curves than both the experimental and domestic samples. The domestic samples were found to have better workability or plasticity at higher temperatures than the imported ones, probably because they were formulated for a tropical climate.
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spelling upm-1126352025-03-06T01:01:58Z http://psasir.upm.edu.my/id/eprint/112635/ Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia Chu, B. S. Ghazali, H. M. Lai, O. M. Che Man, Y. B. Yusof, S. Tee, S. B. Yusoff, M. S. A. A transesterified experimental solid frying shortening was prepared from a palm stearin/palm kernel olein blend at 1:1 ratio (by weight) by using Rhizomucor miehei lipase at 60°C for 6 h. The fatty acid (FA) and triacylglycerol compositions, polymorphic forms, melting and cooling characteristics, slip melting point (SMP), and solid fat content (SFC) of the transesterified blend were then compared with five commercial solid frying shortenings (three domestic and two imported) found in Malaysia. All the domestic shortenings contained nonhydrogenated palm oil or palm olein and palm stearin as the hard stock, whereas the imported frying shortenings were formulated from soybean oil and cottonseed oil and contained high levels of β′ crystals. Trans FA were also found in these samples. The lipase-transesterified blend was found to be more β′-tending than the domestic samples. The SMP of the transesterified blend (47.0°C) fell within the range of the domestic samples (37.8-49.7°C) but was higher than the imported ones (42.3-43.0°C). All samples exhibited similar differential scanning calorimetry cooling profiles, with a narrow peak at the higher temperatures and a broad peak at the lower temperatures, even though their heating thermograms were quite different. Imported samples had flatter SFC curves than both the experimental and domestic samples. The domestic samples were found to have better workability or plasticity at higher temperatures than the imported ones, probably because they were formulated for a tropical climate. Wiley 2001 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/112635/3/112635.pdf Chu, B. S. and Ghazali, H. M. and Lai, O. M. and Che Man, Y. B. and Yusof, S. and Tee, S. B. and Yusoff, M. S. A. (2001) Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia. Journal of the American Oil Chemists' Society, 78 (12). pp. 1213-1219. ISSN 0003-021X; eISSN: 1558-9331 https://aocs.onlinelibrary.wiley.com/doi/10.1007/s11745-001-0416-7 10.1007/s11745-001-0416-7
spellingShingle Chu, B. S.
Ghazali, H. M.
Lai, O. M.
Che Man, Y. B.
Yusof, S.
Tee, S. B.
Yusoff, M. S. A.
Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia
title Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia
title_full Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia
title_fullStr Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia
title_full_unstemmed Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia
title_short Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia
title_sort comparison of lipase-transesterified blend with some commercial solid frying shortenings in malaysia
url http://psasir.upm.edu.my/id/eprint/112635/
http://psasir.upm.edu.my/id/eprint/112635/
http://psasir.upm.edu.my/id/eprint/112635/
http://psasir.upm.edu.my/id/eprint/112635/3/112635.pdf