Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite

A layered organic-inorganic hybrid nanocomposite was prepared by using a surfactant, dioctyl sulphosuccinate (DSS) as a guest in Zn-Al layered double hydroxide (LDH) inorganic host by a self-assembly technique. The ZnAl ratio of the mother liquor was kept constant at 4 at the beginning of the synthe...

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Main Authors: Hussein, Mohd Zobir, Hwa, Tan Kim
Format: Article
Published: Springer 2000
Online Access:http://psasir.upm.edu.my/id/eprint/112415/
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author Hussein, Mohd Zobir
Hwa, Tan Kim
author_facet Hussein, Mohd Zobir
Hwa, Tan Kim
author_sort Hussein, Mohd Zobir
building UPM Institutional Repository
collection Online Access
description A layered organic-inorganic hybrid nanocomposite was prepared by using a surfactant, dioctyl sulphosuccinate (DSS) as a guest in Zn-Al layered double hydroxide (LDH) inorganic host by a self-assembly technique. The ZnAl ratio of the mother liquor was kept constant at 4 at the beginning of the synthesis. Powder X-ray diffractogram shows that the basal spacing of the Zn-Al LDH with sulphate as the intergallery anion (ZASUL) expanded from 11.0 to 26.3 Å to accommodate the DSS surfactant anion for the formation of the Zn-Al LDH-DSS layered organicinorganic hybrid nanocomposite (ZADON). It was also found that the BET surface area reduced by about 90%, from 22.5 to 2.2 m2/g, for ZASUL and ZADON, respectively if 0. 1 M DSS was used for the synthesis of the latter.
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spelling upm-1124152025-02-19T07:10:12Z http://psasir.upm.edu.my/id/eprint/112415/ Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite Hussein, Mohd Zobir Hwa, Tan Kim A layered organic-inorganic hybrid nanocomposite was prepared by using a surfactant, dioctyl sulphosuccinate (DSS) as a guest in Zn-Al layered double hydroxide (LDH) inorganic host by a self-assembly technique. The ZnAl ratio of the mother liquor was kept constant at 4 at the beginning of the synthesis. Powder X-ray diffractogram shows that the basal spacing of the Zn-Al LDH with sulphate as the intergallery anion (ZASUL) expanded from 11.0 to 26.3 Å to accommodate the DSS surfactant anion for the formation of the Zn-Al LDH-DSS layered organicinorganic hybrid nanocomposite (ZADON). It was also found that the BET surface area reduced by about 90%, from 22.5 to 2.2 m2/g, for ZASUL and ZADON, respectively if 0. 1 M DSS was used for the synthesis of the latter. Springer 2000 Article PeerReviewed Hussein, Mohd Zobir and Hwa, Tan Kim (2000) Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite. Journal of Nanoparticle Research, 2 (3). pp. 293-298. ISSN 1388-0764; eISSN: 1572-896X https://link.springer.com/article/10.1023/A:1010013201391?error=cookies_not_supported&code=f0c12066-0b34-4ba9-a35c-f7390267c961 10.1023/a:1010013201391
spellingShingle Hussein, Mohd Zobir
Hwa, Tan Kim
Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite
title Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite
title_full Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite
title_fullStr Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite
title_full_unstemmed Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite
title_short Synthesis and properties of Layered Organic–inorganic Hybrid Material: Zn-Al Layered Double Hydroxide–dioctyl Sulfosuccinate Nanocomposite
title_sort synthesis and properties of layered organic–inorganic hybrid material: zn-al layered double hydroxide–dioctyl sulfosuccinate nanocomposite
url http://psasir.upm.edu.my/id/eprint/112415/
http://psasir.upm.edu.my/id/eprint/112415/
http://psasir.upm.edu.my/id/eprint/112415/