Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B

The BIMEVOX materials can be prepared in four polymorphic modifications: α,β,γ,γ′, depending on Bi: V ratio and the nature/concentration of dopant. Polymorphic transitions take place on heat/cool cycles and can be detected by DTA and by variations in conductivity Arrhenius plots. A survey of thermal...

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Main Authors: Lee, C.K., West, A.R.
Format: Article
Language:English
Published: Elsevier 1996
Online Access:http://psasir.upm.edu.my/id/eprint/111953/
http://psasir.upm.edu.my/id/eprint/111953/3/111953.pdf
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author Lee, C.K.
West, A.R.
author_facet Lee, C.K.
West, A.R.
author_sort Lee, C.K.
building UPM Institutional Repository
collection Online Access
description The BIMEVOX materials can be prepared in four polymorphic modifications: α,β,γ,γ′, depending on Bi: V ratio and the nature/concentration of dopant. Polymorphic transitions take place on heat/cool cycles and can be detected by DTA and by variations in conductivity Arrhenius plots. A survey of thermal behaviour is given, using as examples several new BIMEVOX materials. Some conductivity values at 300 °C are:
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spelling upm-1119532025-03-07T08:18:16Z http://psasir.upm.edu.my/id/eprint/111953/ Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B Lee, C.K. West, A.R. The BIMEVOX materials can be prepared in four polymorphic modifications: α,β,γ,γ′, depending on Bi: V ratio and the nature/concentration of dopant. Polymorphic transitions take place on heat/cool cycles and can be detected by DTA and by variations in conductivity Arrhenius plots. A survey of thermal behaviour is given, using as examples several new BIMEVOX materials. Some conductivity values at 300 °C are: Elsevier 1996 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/111953/3/111953.pdf Lee, C.K. and West, A.R. (1996) Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B. Solid State Ionics, 86-88 (pt.1). pp. 235-239. ISSN 0167-2738; eISSN: 1872-7689 https://linkinghub.elsevier.com/retrieve/pii/0167273896001324 10.1016/0167-2738(96)00132-4
spellingShingle Lee, C.K.
West, A.R.
Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B
title Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B
title_full Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B
title_fullStr Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B
title_full_unstemmed Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B
title_short Thermal behaviour and polymorphism of BIMEVOX oxide ion conductors including the new materials: Bi4V2O11: M; M = La, Y, Mg, B
title_sort thermal behaviour and polymorphism of bimevox oxide ion conductors including the new materials: bi4v2o11: m; m = la, y, mg, b
url http://psasir.upm.edu.my/id/eprint/111953/
http://psasir.upm.edu.my/id/eprint/111953/
http://psasir.upm.edu.my/id/eprint/111953/
http://psasir.upm.edu.my/id/eprint/111953/3/111953.pdf