Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study
Bis(2-chloroethyl)ether, a nonvesicant and easy to handle chemical, was proposed as a model compound for the vesicant sulfur mustard (SM) in routine permeation testing of protective devices. The proposition was based on detailed studies on sorption of these chemicals in elastomers. From the sorption...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2000
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/111880/ http://psasir.upm.edu.my/id/eprint/111880/3/111880.pdf |
| _version_ | 1848865803829510144 |
|---|---|
| author | Dubey, Vinita Gupta, A. K. Maiti, S. N. Rao, N. B. S. N. |
| author_facet | Dubey, Vinita Gupta, A. K. Maiti, S. N. Rao, N. B. S. N. |
| author_sort | Dubey, Vinita |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Bis(2-chloroethyl)ether, a nonvesicant and easy to handle chemical, was proposed as a model compound for the vesicant sulfur mustard (SM) in routine permeation testing of protective devices. The proposition was based on detailed studies on sorption of these chemicals in elastomers. From the sorption plots and permeation parameters, it was found that the model compound diffuses faster than SM, and the diffusion follows Fickian kinetics. Free volume models, such as those developed by Lee and Salame, together with solubility and thermodynamic interaction parameters, validated the observed sorption phenomenon and afforded a criterion for predicting the barrier properties of elastomers |
| first_indexed | 2025-11-15T14:10:31Z |
| format | Article |
| id | upm-111880 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T14:10:31Z |
| publishDate | 2000 |
| publisher | Wiley |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1118802025-03-12T04:01:09Z http://psasir.upm.edu.my/id/eprint/111880/ Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study Dubey, Vinita Gupta, A. K. Maiti, S. N. Rao, N. B. S. N. Bis(2-chloroethyl)ether, a nonvesicant and easy to handle chemical, was proposed as a model compound for the vesicant sulfur mustard (SM) in routine permeation testing of protective devices. The proposition was based on detailed studies on sorption of these chemicals in elastomers. From the sorption plots and permeation parameters, it was found that the model compound diffuses faster than SM, and the diffusion follows Fickian kinetics. Free volume models, such as those developed by Lee and Salame, together with solubility and thermodynamic interaction parameters, validated the observed sorption phenomenon and afforded a criterion for predicting the barrier properties of elastomers Wiley 2000 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/111880/3/111880.pdf Dubey, Vinita and Gupta, A. K. and Maiti, S. N. and Rao, N. B. S. N. (2000) Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study. Journal of Applied Polymer Science, 77 (11). pp. 2472-2479. ISSN 0021-8995; eISSN: 1097-4628 https://onlinelibrary.wiley.com/doi/10.1002/1097-4628(20000912)77:11%3C2472::AID-APP16%3E3.0.CO;2-X 10.1002/1097-4628(20000912)77:11<2472::aid-app16>3.0.co;2-x |
| spellingShingle | Dubey, Vinita Gupta, A. K. Maiti, S. N. Rao, N. B. S. N. Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study |
| title | Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study |
| title_full | Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study |
| title_fullStr | Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study |
| title_full_unstemmed | Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study |
| title_short | Diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: A comparative study |
| title_sort | diffusion and sorption of sulfur mustard and bis(2-chloroethyl)ether in elastomers: a comparative study |
| url | http://psasir.upm.edu.my/id/eprint/111880/ http://psasir.upm.edu.my/id/eprint/111880/ http://psasir.upm.edu.my/id/eprint/111880/ http://psasir.upm.edu.my/id/eprint/111880/3/111880.pdf |