Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network

An artifical neural network (ANN) was applied for the determination of V(V) based on immobilized fatty hydroxamic acid (FHA) in Poly (methyl Methacrylate)(PMMA). Spectraobtained from the V(V)-FHA complex at single wavelengths was used as the input data for the ANN. The V(V)-FHA complex shows a limit...

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Main Authors: Isha, Azizul, Yusof, Nor Azah, Ahmad, Musa, Suhendra, Dedy, Wan Yunus, Wan Md Zin, Zainal, Zulkarnain
Format: Article
Language:English
English
Published: Universiti Putra Malaysia Press 2007
Online Access:http://psasir.upm.edu.my/id/eprint/10898/
http://psasir.upm.edu.my/id/eprint/10898/1/extending_the_range_of_an_Optical_vandium.pdf
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author Isha, Azizul
Yusof, Nor Azah
Ahmad, Musa
Suhendra, Dedy
Wan Yunus, Wan Md Zin
Zainal, Zulkarnain
author_facet Isha, Azizul
Yusof, Nor Azah
Ahmad, Musa
Suhendra, Dedy
Wan Yunus, Wan Md Zin
Zainal, Zulkarnain
author_sort Isha, Azizul
building UPM Institutional Repository
collection Online Access
description An artifical neural network (ANN) was applied for the determination of V(V) based on immobilized fatty hydroxamic acid (FHA) in Poly (methyl Methacrylate)(PMMA). Spectraobtained from the V(V)-FHA complex at single wavelengths was used as the input data for the ANN. The V(V)-FHA complex shows a limited linear dynamic range was extended with low calibration error.A three layer feed forward neural network using backpropagation (BP) algorithm was employed in this study. The input layer consisted of single neurons,30 neurons in hidden a layer and one output neuron was found appropriate for the multivariate calibration used. The network were trained up to 10 000 epochs with 0.003% learning rate. This reagent also provided a good analytical performance with reproducibility characters of the method yeilding relative standard deviation (RSD) of 9.29% and 7.09% for V(V) at concentrations of 50mg/L and 200mg/L, respectively. The limit of detection of the method wa s 8.4mg/L.
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language English
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publishDate 2007
publisher Universiti Putra Malaysia Press
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spelling upm-108982013-05-27T07:47:29Z http://psasir.upm.edu.my/id/eprint/10898/ Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network Isha, Azizul Yusof, Nor Azah Ahmad, Musa Suhendra, Dedy Wan Yunus, Wan Md Zin Zainal, Zulkarnain An artifical neural network (ANN) was applied for the determination of V(V) based on immobilized fatty hydroxamic acid (FHA) in Poly (methyl Methacrylate)(PMMA). Spectraobtained from the V(V)-FHA complex at single wavelengths was used as the input data for the ANN. The V(V)-FHA complex shows a limited linear dynamic range was extended with low calibration error.A three layer feed forward neural network using backpropagation (BP) algorithm was employed in this study. The input layer consisted of single neurons,30 neurons in hidden a layer and one output neuron was found appropriate for the multivariate calibration used. The network were trained up to 10 000 epochs with 0.003% learning rate. This reagent also provided a good analytical performance with reproducibility characters of the method yeilding relative standard deviation (RSD) of 9.29% and 7.09% for V(V) at concentrations of 50mg/L and 200mg/L, respectively. The limit of detection of the method wa s 8.4mg/L. Universiti Putra Malaysia Press 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/10898/1/extending_the_range_of_an_Optical_vandium.pdf Isha, Azizul and Yusof, Nor Azah and Ahmad, Musa and Suhendra, Dedy and Wan Yunus, Wan Md Zin and Zainal, Zulkarnain (2007) Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network. Pertanika Journal of Science & Technology, 15 (2). pp. 121-130. ISSN 0128-7680 English
spellingShingle Isha, Azizul
Yusof, Nor Azah
Ahmad, Musa
Suhendra, Dedy
Wan Yunus, Wan Md Zin
Zainal, Zulkarnain
Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network
title Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network
title_full Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network
title_fullStr Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network
title_full_unstemmed Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network
title_short Extending the range of an Optical Vanadium (V) Sensor Based on Immobilized Fatty Hydroxamic Acid in Poly (methyl Methacrylate) using Artifical Neural Network
title_sort extending the range of an optical vanadium (v) sensor based on immobilized fatty hydroxamic acid in poly (methyl methacrylate) using artifical neural network
url http://psasir.upm.edu.my/id/eprint/10898/
http://psasir.upm.edu.my/id/eprint/10898/1/extending_the_range_of_an_Optical_vandium.pdf