Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating

Vegetable oil has been extensively investigated as a precursor to the eco-friendly coating as an alternative to petrochemical-based resources due to its lower carbon footprint properties. In view of this, jatropha oil (JO), a type of non-edible oil, has received significant attention in this field....

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Main Authors: Li, Wong Jia, Aung, Min Min, Rayung, Marwah, Ngee, Lim Hong, Fui, Mark Lee Wun
Format: Article
Published: Elsevier 2023
Online Access:http://psasir.upm.edu.my/id/eprint/106876/
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author Li, Wong Jia
Aung, Min Min
Rayung, Marwah
Ngee, Lim Hong
Fui, Mark Lee Wun
author_facet Li, Wong Jia
Aung, Min Min
Rayung, Marwah
Ngee, Lim Hong
Fui, Mark Lee Wun
author_sort Li, Wong Jia
building UPM Institutional Repository
collection Online Access
description Vegetable oil has been extensively investigated as a precursor to the eco-friendly coating as an alternative to petrochemical-based resources due to its lower carbon footprint properties. In view of this, jatropha oil (JO), a type of non-edible oil, has received significant attention in this field. The present study was undertaken to utilize acrylated epoxidized jatropha oil (AEJO) resin and to evaluate the anti-corrosion performance with the addition of graphene nanoplatelets (GNP). AEJO-GNP nanocomposites coatings were obtained after three passes of ultraviolet (UV) irradiation. The corrosion protection of all nanocomposites coatings was investigated by electrochemical measurements. The results showed that the corrosion performance of AEJO-GNP nanocomposites coatings improved from the blank coating. Among all coatings tested, AEJO-0.5 wt% GNP exhibited the strongest barrier property and maximum performance in corrosion protection. The result was supported by water contact angle and pull-off adhesion tests. In addition, the highest pull-off adhesion strength for GNP fillers added coatings was established at 0.5 wt% of GNP. High hydrophobicity and pull-off adhesion strength coatings provided a physical barrier that created a tortuosity pathway for corrosive electrolytes to reach the metal surface and thus showed better anti-corrosion resistance. Thus, nanocomposites coatings with 0.5 wt% GNP exhibited the best anti-corrosive efficacy and surface coating property.
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spelling upm-1068762024-08-06T02:55:57Z http://psasir.upm.edu.my/id/eprint/106876/ Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating Li, Wong Jia Aung, Min Min Rayung, Marwah Ngee, Lim Hong Fui, Mark Lee Wun Vegetable oil has been extensively investigated as a precursor to the eco-friendly coating as an alternative to petrochemical-based resources due to its lower carbon footprint properties. In view of this, jatropha oil (JO), a type of non-edible oil, has received significant attention in this field. The present study was undertaken to utilize acrylated epoxidized jatropha oil (AEJO) resin and to evaluate the anti-corrosion performance with the addition of graphene nanoplatelets (GNP). AEJO-GNP nanocomposites coatings were obtained after three passes of ultraviolet (UV) irradiation. The corrosion protection of all nanocomposites coatings was investigated by electrochemical measurements. The results showed that the corrosion performance of AEJO-GNP nanocomposites coatings improved from the blank coating. Among all coatings tested, AEJO-0.5 wt% GNP exhibited the strongest barrier property and maximum performance in corrosion protection. The result was supported by water contact angle and pull-off adhesion tests. In addition, the highest pull-off adhesion strength for GNP fillers added coatings was established at 0.5 wt% of GNP. High hydrophobicity and pull-off adhesion strength coatings provided a physical barrier that created a tortuosity pathway for corrosive electrolytes to reach the metal surface and thus showed better anti-corrosion resistance. Thus, nanocomposites coatings with 0.5 wt% GNP exhibited the best anti-corrosive efficacy and surface coating property. Elsevier 2023 Article PeerReviewed Li, Wong Jia and Aung, Min Min and Rayung, Marwah and Ngee, Lim Hong and Fui, Mark Lee Wun (2023) Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating. Progress in Organic Coatings, 175. pp. 1-10. ISSN 0300-9440; ESSN: 1873-331X https://www.sciencedirect.com/science/article/pii/S0300944022006464 10.1016/j.porgcoat.2022.107349
spellingShingle Li, Wong Jia
Aung, Min Min
Rayung, Marwah
Ngee, Lim Hong
Fui, Mark Lee Wun
Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_full Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_fullStr Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_full_unstemmed Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_short Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_sort bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
url http://psasir.upm.edu.my/id/eprint/106876/
http://psasir.upm.edu.my/id/eprint/106876/
http://psasir.upm.edu.my/id/eprint/106876/