Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis
Many MOFs based on various metal ions including s-, p-, d-, and f-block elements have been developed over the past decade. Despite their abundance, low cost, and non-toxicity, s-block MOFs have been explored less frequently than those based on transition metals and f-block metal ions. Sequential cal...
| Main Authors: | , , , , , |
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| Format: | Article |
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Elsevier
2024
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| Online Access: | http://psasir.upm.edu.my/id/eprint/106163/ |
| _version_ | 1848864705564639232 |
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| author | Roslan, Muhammad Qusyairi Jori Aris, Ahmad Zaharin Abdul Rahman, Mohd Basyaruddin Ngee, Lim Hong Mohd Isa, Noorain Ahmad Aljafree, Nurul Farhana |
| author_facet | Roslan, Muhammad Qusyairi Jori Aris, Ahmad Zaharin Abdul Rahman, Mohd Basyaruddin Ngee, Lim Hong Mohd Isa, Noorain Ahmad Aljafree, Nurul Farhana |
| author_sort | Roslan, Muhammad Qusyairi Jori |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Many MOFs based on various metal ions including s-, p-, d-, and f-block elements have been developed over the past decade. Despite their abundance, low cost, and non-toxicity, s-block MOFs have been explored less frequently than those based on transition metals and f-block metal ions. Sequential calcium carboxylate-based linker MOFs (Ca-MOFs) were successfully synthesized and constructed using a solvothermal system and coordination bonding. Sequential Ca-MOFs were subjected to 13 different environments to thoroughly examine their framework stability. The investigation demonstrated a calcium-carboxylate-based linker possessing superior robustness towards hydrolysis, Brønsted–Lowry acid–bases, and polarity stability from crystallite modification through the XRD spectrum before and after exposure. In this study, the Ca-H2BDC framework was found to be highly chemically stable with almost no observed crystallite modifications. The stability of sequential calcium-carboxylate-based linker MOFs reflects strong coordination bonding according to the hard soft acid base (HSAB) principle. |
| first_indexed | 2025-11-15T13:53:04Z |
| format | Article |
| id | upm-106163 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T13:53:04Z |
| publishDate | 2024 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1061632024-09-11T03:14:48Z http://psasir.upm.edu.my/id/eprint/106163/ Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis Roslan, Muhammad Qusyairi Jori Aris, Ahmad Zaharin Abdul Rahman, Mohd Basyaruddin Ngee, Lim Hong Mohd Isa, Noorain Ahmad Aljafree, Nurul Farhana Many MOFs based on various metal ions including s-, p-, d-, and f-block elements have been developed over the past decade. Despite their abundance, low cost, and non-toxicity, s-block MOFs have been explored less frequently than those based on transition metals and f-block metal ions. Sequential calcium carboxylate-based linker MOFs (Ca-MOFs) were successfully synthesized and constructed using a solvothermal system and coordination bonding. Sequential Ca-MOFs were subjected to 13 different environments to thoroughly examine their framework stability. The investigation demonstrated a calcium-carboxylate-based linker possessing superior robustness towards hydrolysis, Brønsted–Lowry acid–bases, and polarity stability from crystallite modification through the XRD spectrum before and after exposure. In this study, the Ca-H2BDC framework was found to be highly chemically stable with almost no observed crystallite modifications. The stability of sequential calcium-carboxylate-based linker MOFs reflects strong coordination bonding according to the hard soft acid base (HSAB) principle. Elsevier 2024-05 Article PeerReviewed Roslan, Muhammad Qusyairi Jori and Aris, Ahmad Zaharin and Abdul Rahman, Mohd Basyaruddin and Ngee, Lim Hong and Mohd Isa, Noorain and Ahmad Aljafree, Nurul Farhana (2024) Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis. Journal of Molecular Structure, 1303. ISSN 0022-2860; ESSN: 1872-8014 https://linkinghub.elsevier.com/retrieve/pii/S0022286024000899 10.1016/j.molstruc.2024.137566 |
| spellingShingle | Roslan, Muhammad Qusyairi Jori Aris, Ahmad Zaharin Abdul Rahman, Mohd Basyaruddin Ngee, Lim Hong Mohd Isa, Noorain Ahmad Aljafree, Nurul Farhana Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis |
| title | Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis |
| title_full | Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis |
| title_fullStr | Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis |
| title_full_unstemmed | Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis |
| title_short | Mechanistic synthesis of a sequential calcium-carboxylate-based linker (Ca-MOFs) and rapid assessment of chemical stability through XRD analysis |
| title_sort | mechanistic synthesis of a sequential calcium-carboxylate-based linker (ca-mofs) and rapid assessment of chemical stability through xrd analysis |
| url | http://psasir.upm.edu.my/id/eprint/106163/ http://psasir.upm.edu.my/id/eprint/106163/ http://psasir.upm.edu.my/id/eprint/106163/ |