Development of porous MIL-101 derived catalyst application for green diesel production
A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to...
| Main Authors: | , , , , |
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| Format: | Article |
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Elsevier Ltd
2024
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| Online Access: | http://psasir.upm.edu.my/id/eprint/105850/ |
| _version_ | 1848864625046585344 |
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| author | Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. |
| author_facet | Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. |
| author_sort | Chang, He |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 with Ni loading > 8 wt on P-MIL-101. In addition, both 25 and 14 wt Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production. |
| first_indexed | 2025-11-15T13:51:47Z |
| format | Article |
| id | upm-105850 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T13:51:47Z |
| publishDate | 2024 |
| publisher | Elsevier Ltd |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-1058502024-03-29T03:36:55Z http://psasir.upm.edu.my/id/eprint/105850/ Development of porous MIL-101 derived catalyst application for green diesel production Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 with Ni loading > 8 wt on P-MIL-101. In addition, both 25 and 14 wt Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production. Elsevier Ltd 2024 Article PeerReviewed Chang, He and Abdulkareem-Alsultan, G. and Taufiq-Yap, Y.H. and Mohd Izham, S. and Sivasangar, S. (2024) Development of porous MIL-101 derived catalyst application for green diesel production. Fuel, 355. art. no. 129459. pp. 1-21. ISSN 0016-2361; ESSN: 1873-7153 https://www.sciencedirect.com/science/article/pii/S0016236123020732 10.1016/j.fuel.2023.129459 |
| spellingShingle | Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. Development of porous MIL-101 derived catalyst application for green diesel production |
| title | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_full | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_fullStr | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_full_unstemmed | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_short | Development of porous MIL-101 derived catalyst application for green diesel production |
| title_sort | development of porous mil-101 derived catalyst application for green diesel production |
| url | http://psasir.upm.edu.my/id/eprint/105850/ http://psasir.upm.edu.my/id/eprint/105850/ http://psasir.upm.edu.my/id/eprint/105850/ |