Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system

Nanoscale calcium peroxide (nCP) has turned out to be one of the effective and environmentally friendly approaches for wastewater remediation purposes. The rapid hydrolysis of nCPs and burst oxygen release caused by the high surface-to-volume ratio of nCPs could surpass the appropriate demand for ox...

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Main Authors: Amerhaider Nuar, Nurul Nazihah, Md. Jamil, Siti Nurul Ain, Li, Fan, Mat Azmi, Intan Diana, Chiang, Pen Chi, Shean, Thomas Yaw Choong
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2022
Online Access:http://psasir.upm.edu.my/id/eprint/103403/
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author Amerhaider Nuar, Nurul Nazihah
Md. Jamil, Siti Nurul Ain
Li, Fan
Mat Azmi, Intan Diana
Chiang, Pen Chi
Shean, Thomas Yaw Choong
author_facet Amerhaider Nuar, Nurul Nazihah
Md. Jamil, Siti Nurul Ain
Li, Fan
Mat Azmi, Intan Diana
Chiang, Pen Chi
Shean, Thomas Yaw Choong
author_sort Amerhaider Nuar, Nurul Nazihah
building UPM Institutional Repository
collection Online Access
description Nanoscale calcium peroxide (nCP) has turned out to be one of the effective and environmentally friendly approaches for wastewater remediation purposes. The rapid hydrolysis of nCPs and burst oxygen release caused by the high surface-to-volume ratio of nCPs could surpass the appropriate demand for oxygenation and pollutant degradation in the aqueous system. Thus, coated oxidants (COs) have been prepared using polymeric materials to ensure long-term efficacy and slow-release capability. Therefore, the nCPs were first prepared using dextran as a stabilizer to prevent irreversible agglomeration by the chemical precipitation method and had an average mean size of 2.33 ± 0.81 nm. The synthesized nCPs were then coated with dextran to produce dextran-coated nCPs. Their characteristics and effectiveness in doxycycline (DOX) degradation were assessed. The characterization of nCPs and dextran-coated nCPs was performed using X-ray diffractometry (XRD), field emission scanning electron microscopy (FESEM), fourier transform infrared spectroscopy (FTIR), Brunauer, Emmett and Teller analysis (BET), dynamic light scattering (DLS) and thermogravimetric analysis (TGA) techniques. This work suggests that dextran-coated nCPs are beneficial in wastewater treatment practice in terms of the long-term efficacy of DOX degradation potential.
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institution Universiti Putra Malaysia
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spelling upm-1034032023-06-09T02:20:53Z http://psasir.upm.edu.my/id/eprint/103403/ Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system Amerhaider Nuar, Nurul Nazihah Md. Jamil, Siti Nurul Ain Li, Fan Mat Azmi, Intan Diana Chiang, Pen Chi Shean, Thomas Yaw Choong Nanoscale calcium peroxide (nCP) has turned out to be one of the effective and environmentally friendly approaches for wastewater remediation purposes. The rapid hydrolysis of nCPs and burst oxygen release caused by the high surface-to-volume ratio of nCPs could surpass the appropriate demand for oxygenation and pollutant degradation in the aqueous system. Thus, coated oxidants (COs) have been prepared using polymeric materials to ensure long-term efficacy and slow-release capability. Therefore, the nCPs were first prepared using dextran as a stabilizer to prevent irreversible agglomeration by the chemical precipitation method and had an average mean size of 2.33 ± 0.81 nm. The synthesized nCPs were then coated with dextran to produce dextran-coated nCPs. Their characteristics and effectiveness in doxycycline (DOX) degradation were assessed. The characterization of nCPs and dextran-coated nCPs was performed using X-ray diffractometry (XRD), field emission scanning electron microscopy (FESEM), fourier transform infrared spectroscopy (FTIR), Brunauer, Emmett and Teller analysis (BET), dynamic light scattering (DLS) and thermogravimetric analysis (TGA) techniques. This work suggests that dextran-coated nCPs are beneficial in wastewater treatment practice in terms of the long-term efficacy of DOX degradation potential. Multidisciplinary Digital Publishing Institute 2022 Article PeerReviewed Amerhaider Nuar, Nurul Nazihah and Md. Jamil, Siti Nurul Ain and Li, Fan and Mat Azmi, Intan Diana and Chiang, Pen Chi and Shean, Thomas Yaw Choong (2022) Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system. Polymers, 14 (18). art. no. 3866. pp. 1-18. ISSN 2073-4360 https://www.mdpi.com/2073-4360/14/18/3866 10.3390/polym14183866
spellingShingle Amerhaider Nuar, Nurul Nazihah
Md. Jamil, Siti Nurul Ain
Li, Fan
Mat Azmi, Intan Diana
Chiang, Pen Chi
Shean, Thomas Yaw Choong
Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system
title Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system
title_full Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system
title_fullStr Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system
title_full_unstemmed Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system
title_short Synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system
title_sort synthesis of controlled-release calcium peroxide nanoparticles coated with dextran for removal of doxycycline from aqueous system
url http://psasir.upm.edu.my/id/eprint/103403/
http://psasir.upm.edu.my/id/eprint/103403/
http://psasir.upm.edu.my/id/eprint/103403/