Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization

High oil sorption, dynamic oil/water selectivity and oil retention are essential for advanced materials to remediate offshore oil spills. In this context, superoleophilic-hydrophobic kapok bundles, synthesized via a simple, one-step and energy efficient carbonization (300°C), were investigated as ef...

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Main Authors: Yunos, Normaisarah, Müller, Julian, Chen, Soo Kien, Tan, Kar Ban, Hepp, Marco, Butz, Benjamin, Schönherr, Holger, Talib, Zainal Abidin, Md Salim, Nora Salina, Mohd Ghazali, Mohd Sabri, Lee, Oon Jew
Format: Article
Published: Taylor and Francis 2022
Online Access:http://psasir.upm.edu.my/id/eprint/103361/
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author Yunos, Normaisarah
Müller, Julian
Chen, Soo Kien
Tan, Kar Ban
Hepp, Marco
Butz, Benjamin
Schönherr, Holger
Talib, Zainal Abidin
Md Salim, Nora Salina
Mohd Ghazali, Mohd Sabri
Lee, Oon Jew
author_facet Yunos, Normaisarah
Müller, Julian
Chen, Soo Kien
Tan, Kar Ban
Hepp, Marco
Butz, Benjamin
Schönherr, Holger
Talib, Zainal Abidin
Md Salim, Nora Salina
Mohd Ghazali, Mohd Sabri
Lee, Oon Jew
author_sort Yunos, Normaisarah
building UPM Institutional Repository
collection Online Access
description High oil sorption, dynamic oil/water selectivity and oil retention are essential for advanced materials to remediate offshore oil spills. In this context, superoleophilic-hydrophobic kapok bundles, synthesized via a simple, one-step and energy efficient carbonization (300°C), were investigated as effective oil sorbents. It was shown that the surface roughness and intrinsic graphite phase of the kapok bundles were tunable by varying the carbonization temperature, thereby enhancing their oil sorption and retention. Lumen preservation enables the carbonaceous kapok bundles to exhibit tunable oil sorption capacities of 34.0 g/g – 95.5 g/g for various types of oil, unrivaled among other oil spill recovery methods. The origin of oil permeability into lumen is attributed to nanopores observed for the first time on the carbonaceous kapok fibers. The kapok bundles selectively absorbed oil slick under vigorous water vortex and demonstrated distinctly high oil retention of 100% under gravitation force. Multiple oil sorption-desorption and compression cycles (up to 15 times) demonstrate a considerable promise of the carbonaceous kapok bundles for high reusability with low environmental impact.
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institution Universiti Putra Malaysia
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spelling upm-1033612023-06-19T04:26:02Z http://psasir.upm.edu.my/id/eprint/103361/ Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization Yunos, Normaisarah Müller, Julian Chen, Soo Kien Tan, Kar Ban Hepp, Marco Butz, Benjamin Schönherr, Holger Talib, Zainal Abidin Md Salim, Nora Salina Mohd Ghazali, Mohd Sabri Lee, Oon Jew High oil sorption, dynamic oil/water selectivity and oil retention are essential for advanced materials to remediate offshore oil spills. In this context, superoleophilic-hydrophobic kapok bundles, synthesized via a simple, one-step and energy efficient carbonization (300°C), were investigated as effective oil sorbents. It was shown that the surface roughness and intrinsic graphite phase of the kapok bundles were tunable by varying the carbonization temperature, thereby enhancing their oil sorption and retention. Lumen preservation enables the carbonaceous kapok bundles to exhibit tunable oil sorption capacities of 34.0 g/g – 95.5 g/g for various types of oil, unrivaled among other oil spill recovery methods. The origin of oil permeability into lumen is attributed to nanopores observed for the first time on the carbonaceous kapok fibers. The kapok bundles selectively absorbed oil slick under vigorous water vortex and demonstrated distinctly high oil retention of 100% under gravitation force. Multiple oil sorption-desorption and compression cycles (up to 15 times) demonstrate a considerable promise of the carbonaceous kapok bundles for high reusability with low environmental impact. Taylor and Francis 2022 Article PeerReviewed Yunos, Normaisarah and Müller, Julian and Chen, Soo Kien and Tan, Kar Ban and Hepp, Marco and Butz, Benjamin and Schönherr, Holger and Talib, Zainal Abidin and Md Salim, Nora Salina and Mohd Ghazali, Mohd Sabri and Lee, Oon Jew (2022) Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization. Journal of Natural Fibers, 19 (15). pp. 12398-12414. ISSN 1544-0478; ESSN: 1544-046X https://www.tandfonline.com/doi/abs/10.1080/15440478.2022.2060403 10.1080/15440478.2022.2060403
spellingShingle Yunos, Normaisarah
Müller, Julian
Chen, Soo Kien
Tan, Kar Ban
Hepp, Marco
Butz, Benjamin
Schönherr, Holger
Talib, Zainal Abidin
Md Salim, Nora Salina
Mohd Ghazali, Mohd Sabri
Lee, Oon Jew
Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization
title Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization
title_full Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization
title_fullStr Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization
title_full_unstemmed Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization
title_short Superoleophilic-hydrophobic Kapok oil sorbents via energy efficient carbonization
title_sort superoleophilic-hydrophobic kapok oil sorbents via energy efficient carbonization
url http://psasir.upm.edu.my/id/eprint/103361/
http://psasir.upm.edu.my/id/eprint/103361/
http://psasir.upm.edu.my/id/eprint/103361/