Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9

In nature, aldehyde dehydrogenase (ALDH) is widely distributed and mainly involved in the oxidation of aldehydes. Thermostability is one of the key features for industrial enzymes. The ability of enzymes to withstand a high operating temperature offers many advantages, including enhancing productivi...

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Main Authors: Rosli, Nur Ezzati, Mohamad Ali, Mohd Shukuri, Ahmad Kamarudin, Nor Hafizah, Masomian, Malihe, Latip, Wahhida, Saadon, Shazleen, Raja Abd Rahman, Raja Noor Zaliha
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2022
Online Access:http://psasir.upm.edu.my/id/eprint/103327/
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author Rosli, Nur Ezzati
Mohamad Ali, Mohd Shukuri
Ahmad Kamarudin, Nor Hafizah
Masomian, Malihe
Latip, Wahhida
Saadon, Shazleen
Raja Abd Rahman, Raja Noor Zaliha
author_facet Rosli, Nur Ezzati
Mohamad Ali, Mohd Shukuri
Ahmad Kamarudin, Nor Hafizah
Masomian, Malihe
Latip, Wahhida
Saadon, Shazleen
Raja Abd Rahman, Raja Noor Zaliha
author_sort Rosli, Nur Ezzati
building UPM Institutional Repository
collection Online Access
description In nature, aldehyde dehydrogenase (ALDH) is widely distributed and mainly involved in the oxidation of aldehydes. Thermostability is one of the key features for industrial enzymes. The ability of enzymes to withstand a high operating temperature offers many advantages, including enhancing productivity in industries. This study was conducted to understand the structural and biochemical features of ALDH from thermophilic bacterium, Anoxybacillus geothermalis strain D9. The 3D structure of A. geothermalis ALDH was predicted by YASARA software and composed of 24.3% β-sheet located at the center core region. The gene, which encodes 504 amino acids with a molecular weight of ~56 kDa, was cloned into pET51b(+) and expressed in E.coli Transetta (DE3). The purified A. geothermalis ALDH showed remarkable thermostability with optimum temperature at 60 °C and stable at 70 °C for 1 h. The melting point of the A. geothermalis ALDH is at 65.9 °C. Metal ions such as Fe3+ ions inhibited the enzyme activity, while Li+ and Mg2+ enhanced by 38.83% and 105.83%, respectively. Additionally, this enzyme showed tolerance to most non-polar organic solvents tested (xylene, n-dedocane, n-tetradecane, n-hexadecane) in a concentration of 25% v/v. These findings have generally improved the understanding of thermostable A. geothermalis ALDH so it can be widely used in the industry.
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spelling upm-1033272023-11-02T03:49:53Z http://psasir.upm.edu.my/id/eprint/103327/ Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9 Rosli, Nur Ezzati Mohamad Ali, Mohd Shukuri Ahmad Kamarudin, Nor Hafizah Masomian, Malihe Latip, Wahhida Saadon, Shazleen Raja Abd Rahman, Raja Noor Zaliha In nature, aldehyde dehydrogenase (ALDH) is widely distributed and mainly involved in the oxidation of aldehydes. Thermostability is one of the key features for industrial enzymes. The ability of enzymes to withstand a high operating temperature offers many advantages, including enhancing productivity in industries. This study was conducted to understand the structural and biochemical features of ALDH from thermophilic bacterium, Anoxybacillus geothermalis strain D9. The 3D structure of A. geothermalis ALDH was predicted by YASARA software and composed of 24.3% β-sheet located at the center core region. The gene, which encodes 504 amino acids with a molecular weight of ~56 kDa, was cloned into pET51b(+) and expressed in E.coli Transetta (DE3). The purified A. geothermalis ALDH showed remarkable thermostability with optimum temperature at 60 °C and stable at 70 °C for 1 h. The melting point of the A. geothermalis ALDH is at 65.9 °C. Metal ions such as Fe3+ ions inhibited the enzyme activity, while Li+ and Mg2+ enhanced by 38.83% and 105.83%, respectively. Additionally, this enzyme showed tolerance to most non-polar organic solvents tested (xylene, n-dedocane, n-tetradecane, n-hexadecane) in a concentration of 25% v/v. These findings have generally improved the understanding of thermostable A. geothermalis ALDH so it can be widely used in the industry. Multidisciplinary Digital Publishing Institute 2022 Article PeerReviewed Rosli, Nur Ezzati and Mohamad Ali, Mohd Shukuri and Ahmad Kamarudin, Nor Hafizah and Masomian, Malihe and Latip, Wahhida and Saadon, Shazleen and Raja Abd Rahman, Raja Noor Zaliha (2022) Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9. Microorganisms, 10 (7). art. no. 1444. pp. 1-17. ISSN 2076-2607 https://www.mdpi.com/2076-2607/10/7/1444 10.3390/microorganisms10071444
spellingShingle Rosli, Nur Ezzati
Mohamad Ali, Mohd Shukuri
Ahmad Kamarudin, Nor Hafizah
Masomian, Malihe
Latip, Wahhida
Saadon, Shazleen
Raja Abd Rahman, Raja Noor Zaliha
Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9
title Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9
title_full Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9
title_fullStr Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9
title_full_unstemmed Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9
title_short Structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated Anoxybacillus geothermalis strain D9
title_sort structure prediction and characterization of thermostable aldehyde dehydrogenase from newly isolated anoxybacillus geothermalis strain d9
url http://psasir.upm.edu.my/id/eprint/103327/
http://psasir.upm.edu.my/id/eprint/103327/
http://psasir.upm.edu.my/id/eprint/103327/