Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization

Lignin with a phenolic structure can act as a fire retardant, but different origins of lignin and extraction methods impact the fire behavior capabilities. The thermal characteristics of lignin, such as glass transition (Tg) temperature, thermal degradation, molecular weight, lignin purity, and phen...

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Main Authors: Solihat, Nissa Nurfajrin, Hidayat, Alif Faturahman, Mohammad Taib, Mohamad Nurul Azman, Hussin, M. Hazwan, Lee, Seng Hua, Abd Ghani, Muhammad Aizat, Al Edrus, Syeed Saifulazry Osman, Vahabi, Henri, Fatriasari, Widya
Format: Article
Published: Springer 2022
Online Access:http://psasir.upm.edu.my/id/eprint/103007/
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author Solihat, Nissa Nurfajrin
Hidayat, Alif Faturahman
Mohammad Taib, Mohamad Nurul Azman
Hussin, M. Hazwan
Lee, Seng Hua
Abd Ghani, Muhammad Aizat
Al Edrus, Syeed Saifulazry Osman
Vahabi, Henri
Fatriasari, Widya
author_facet Solihat, Nissa Nurfajrin
Hidayat, Alif Faturahman
Mohammad Taib, Mohamad Nurul Azman
Hussin, M. Hazwan
Lee, Seng Hua
Abd Ghani, Muhammad Aizat
Al Edrus, Syeed Saifulazry Osman
Vahabi, Henri
Fatriasari, Widya
author_sort Solihat, Nissa Nurfajrin
building UPM Institutional Repository
collection Online Access
description Lignin with a phenolic structure can act as a fire retardant, but different origins of lignin and extraction methods impact the fire behavior capabilities. The thermal characteristics of lignin, such as glass transition (Tg) temperature, thermal degradation, molecular weight, lignin purity, and phenolic content, influence the capability of lignin as a flame retardant (FR) by causing significant char residue. However, lignin faced significant constraints in the final polymer to meet industry requirements, with the main issue being a lack of homogeneity when blending lignin with polymeric matrices. To improve the FR performance of lignin, various advances have been taken such as altering lignin with nitrogen and/or phosphorus chemicals, as well as shrinking lignin to the nanoscale to reduce lignin aggregation with matrices and obtaining considerable FR behavior in which FR system, lignin can present as a single component, lignin-based composite, modified lignin, and nano lignin. The present review addresses the manufacture of lignin as FR and the attributes of the product with lignin added to the system. It also covers the structure, source, extraction technique, physical-chemical properties, and chemical modification of lignin as an FR source, as well as the basic principle of flame retardancy, influencing factors (current development and application till the industrial analysis need of FR). Throughout this review, it aids in the discovery of a better strategy to introduce lignin as a source of bio-based FR for achieving the low cost in the fabrication method of FR.
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institution Universiti Putra Malaysia
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last_indexed 2025-11-15T13:40:32Z
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spelling upm-1030072024-06-30T07:05:01Z http://psasir.upm.edu.my/id/eprint/103007/ Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization Solihat, Nissa Nurfajrin Hidayat, Alif Faturahman Mohammad Taib, Mohamad Nurul Azman Hussin, M. Hazwan Lee, Seng Hua Abd Ghani, Muhammad Aizat Al Edrus, Syeed Saifulazry Osman Vahabi, Henri Fatriasari, Widya Lignin with a phenolic structure can act as a fire retardant, but different origins of lignin and extraction methods impact the fire behavior capabilities. The thermal characteristics of lignin, such as glass transition (Tg) temperature, thermal degradation, molecular weight, lignin purity, and phenolic content, influence the capability of lignin as a flame retardant (FR) by causing significant char residue. However, lignin faced significant constraints in the final polymer to meet industry requirements, with the main issue being a lack of homogeneity when blending lignin with polymeric matrices. To improve the FR performance of lignin, various advances have been taken such as altering lignin with nitrogen and/or phosphorus chemicals, as well as shrinking lignin to the nanoscale to reduce lignin aggregation with matrices and obtaining considerable FR behavior in which FR system, lignin can present as a single component, lignin-based composite, modified lignin, and nano lignin. The present review addresses the manufacture of lignin as FR and the attributes of the product with lignin added to the system. It also covers the structure, source, extraction technique, physical-chemical properties, and chemical modification of lignin as an FR source, as well as the basic principle of flame retardancy, influencing factors (current development and application till the industrial analysis need of FR). Throughout this review, it aids in the discovery of a better strategy to introduce lignin as a source of bio-based FR for achieving the low cost in the fabrication method of FR. Springer 2022 Article PeerReviewed Solihat, Nissa Nurfajrin and Hidayat, Alif Faturahman and Mohammad Taib, Mohamad Nurul Azman and Hussin, M. Hazwan and Lee, Seng Hua and Abd Ghani, Muhammad Aizat and Al Edrus, Syeed Saifulazry Osman and Vahabi, Henri and Fatriasari, Widya (2022) Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization. Journal of polymers and the environment, 30 (11). pp. 4517-4537. ISSN 1566-2543; ESSN: 1572-8919 https://link.springer.com/article/10.1007/s10924-022-02494-2?error=cookies_not_supported&code=2575e09e-95d4-4ba8-9501-0e97e4d24f76 10.1007/s10924-022-02494-2
spellingShingle Solihat, Nissa Nurfajrin
Hidayat, Alif Faturahman
Mohammad Taib, Mohamad Nurul Azman
Hussin, M. Hazwan
Lee, Seng Hua
Abd Ghani, Muhammad Aizat
Al Edrus, Syeed Saifulazry Osman
Vahabi, Henri
Fatriasari, Widya
Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization
title Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization
title_full Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization
title_fullStr Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization
title_full_unstemmed Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization
title_short Recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization
title_sort recent developments in flame-retardant lignin-based biocomposite: manufacturing, and characterization
url http://psasir.upm.edu.my/id/eprint/103007/
http://psasir.upm.edu.my/id/eprint/103007/
http://psasir.upm.edu.my/id/eprint/103007/