Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy

In this study, surface plasmon resonance (SPR) technique has been utilized to characterize the optical properties of chitosan-graphene quantum dots (CS-GQDs) thin film and dopamine (DA). Theoretical fitting of SPR dips yielded refractive indices of DA solutions and CS-GQDs thin films, as well as the...

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Main Authors: Kamal Eddin, Faten Bashar, Yap, Wing Fen, Sadrolhosseini, Amir Reza, Liew, Josephine Ying Chyi, Mohd Daniyal, Wan Mohd Ebtisyam Mustaqim
Format: Article
Published: Springer New York 2022
Online Access:http://psasir.upm.edu.my/id/eprint/102397/
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author Kamal Eddin, Faten Bashar
Yap, Wing Fen
Sadrolhosseini, Amir Reza
Liew, Josephine Ying Chyi
Mohd Daniyal, Wan Mohd Ebtisyam Mustaqim
author_facet Kamal Eddin, Faten Bashar
Yap, Wing Fen
Sadrolhosseini, Amir Reza
Liew, Josephine Ying Chyi
Mohd Daniyal, Wan Mohd Ebtisyam Mustaqim
author_sort Kamal Eddin, Faten Bashar
building UPM Institutional Repository
collection Online Access
description In this study, surface plasmon resonance (SPR) technique has been utilized to characterize the optical properties of chitosan-graphene quantum dots (CS-GQDs) thin film and dopamine (DA). Theoretical fitting of SPR dips yielded refractive indices of DA solutions and CS-GQDs thin films, as well as the thickness of the thin film. For DA solution, n and k values were the same as deionized water for all concentrations. The values of n and k for CS-GQDs thin film were 1.6990 and 0.1302 respectively before contacting DA. The experimental SPR reflectance curves obtained using CS-GQDs thin film were shifted continuously to the right with increasing DA concentrations. After adsorption of DA molecules, both n and thickness of the CS-GQDs thin film increased, while the value of k decreased. This, in turns, enhanced the SPR sensitivity towards DA. The obtained results underscore the appropriate and sufficient potential of the used technique to measure refractive index variations in real-time when very low concentration was used (1 fM) with refractive index sensitivity of 10.186°/RIU.
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institution Universiti Putra Malaysia
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publishDate 2022
publisher Springer New York
recordtype eprints
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spelling upm-1023972023-05-18T03:17:48Z http://psasir.upm.edu.my/id/eprint/102397/ Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy Kamal Eddin, Faten Bashar Yap, Wing Fen Sadrolhosseini, Amir Reza Liew, Josephine Ying Chyi Mohd Daniyal, Wan Mohd Ebtisyam Mustaqim In this study, surface plasmon resonance (SPR) technique has been utilized to characterize the optical properties of chitosan-graphene quantum dots (CS-GQDs) thin film and dopamine (DA). Theoretical fitting of SPR dips yielded refractive indices of DA solutions and CS-GQDs thin films, as well as the thickness of the thin film. For DA solution, n and k values were the same as deionized water for all concentrations. The values of n and k for CS-GQDs thin film were 1.6990 and 0.1302 respectively before contacting DA. The experimental SPR reflectance curves obtained using CS-GQDs thin film were shifted continuously to the right with increasing DA concentrations. After adsorption of DA molecules, both n and thickness of the CS-GQDs thin film increased, while the value of k decreased. This, in turns, enhanced the SPR sensitivity towards DA. The obtained results underscore the appropriate and sufficient potential of the used technique to measure refractive index variations in real-time when very low concentration was used (1 fM) with refractive index sensitivity of 10.186°/RIU. Springer New York 2022-06-27 Article PeerReviewed Kamal Eddin, Faten Bashar and Yap, Wing Fen and Sadrolhosseini, Amir Reza and Liew, Josephine Ying Chyi and Mohd Daniyal, Wan Mohd Ebtisyam Mustaqim (2022) Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy. Plasmonics, 17. 1985 - 9197. ISSN 1557-1955; ESSN: 1557-1963 https://link.springer.com/article/10.1007/s11468-022-01680-1 10.1007/s11468-022-01680-1
spellingShingle Kamal Eddin, Faten Bashar
Yap, Wing Fen
Sadrolhosseini, Amir Reza
Liew, Josephine Ying Chyi
Mohd Daniyal, Wan Mohd Ebtisyam Mustaqim
Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy
title Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy
title_full Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy
title_fullStr Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy
title_full_unstemmed Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy
title_short Optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy
title_sort optical property analysis of chitosan-graphene quantum dots thin film and dopamine using surface plasmon resonance spectroscopy
url http://psasir.upm.edu.my/id/eprint/102397/
http://psasir.upm.edu.my/id/eprint/102397/
http://psasir.upm.edu.my/id/eprint/102397/