Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria

A popular eco-tourist destination happy haven, renowned for its distinctive groundwater springs, wildlife population and endowed with notable archeologic monuments and other appealing characteristics, thus the need for a baseline survey of the physiochemical measurements to ascertain the concentrati...

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Main Authors: Jabbo, Josiah Nuhu, Mohd Isa, Noorain, Aris, Ahmad Zaharin, Ramli, Mohammad Firuz, Abubakar, Mohammed Bello
Format: Article
Published: Elsevier 2022
Online Access:http://psasir.upm.edu.my/id/eprint/101626/
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author Jabbo, Josiah Nuhu
Mohd Isa, Noorain
Aris, Ahmad Zaharin
Ramli, Mohammad Firuz
Abubakar, Mohammed Bello
author_facet Jabbo, Josiah Nuhu
Mohd Isa, Noorain
Aris, Ahmad Zaharin
Ramli, Mohammad Firuz
Abubakar, Mohammed Bello
author_sort Jabbo, Josiah Nuhu
building UPM Institutional Repository
collection Online Access
description A popular eco-tourist destination happy haven, renowned for its distinctive groundwater springs, wildlife population and endowed with notable archeologic monuments and other appealing characteristics, thus the need for a baseline survey of the physiochemical measurements to ascertain the concentrations of major cations and heavy metals (Cd, Co, Cr, Cu, Fe, Li, Mn, Ni, and Pb)), their distribution across the sampling locations and to investigate the origin of Potentially Toxic Elements (PTEs) due to threats from anthropogenic and geogenic processes to its quality to evaluating its suitability for drinking, and the risk imposed on human health through the use of Water Quality Index (WQI), Hazard Quotient (HQ) and Hazard Index (HI). Concentrations of forty-one water samples from twenty natural springs, fifteen boreholes, five hand-dug wells, and a stream a were detected. Nine heavy metals (Fe, Mn, Li, Cd, Co, Cr, Cu, Pb, and Ni) were analysed with Flame Atomic Absorption Spectrometry (FAAS) and the data using different multivariate statistical approaches. Five component types; 24.40%, 14.50%, 12.10%, 9.64% and 9.24% extracted accounted for 69.79% total variance. The dominant variables derived from PCA's five components indicated the influence of the weathering of anhydrous carbonate, which released major cations and the PTEs. Calculated HQs and HI for adults and children were generally less than one (HQ < 1), indicating less or no potential carcinogenic, except for a heavy metal Cd. It exhibits an HQ and HI > 1, for children ingesting water from all the water sources. Hand-dug wells and surface water from the stream had HQ and HI > 1 for Cd for adults, which may not be harmful but with overtime exposure and may require monitoring; otherwise, it may pose more threats to adults and children with time.
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spelling upm-1016262023-08-15T04:13:38Z http://psasir.upm.edu.my/id/eprint/101626/ Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria Jabbo, Josiah Nuhu Mohd Isa, Noorain Aris, Ahmad Zaharin Ramli, Mohammad Firuz Abubakar, Mohammed Bello A popular eco-tourist destination happy haven, renowned for its distinctive groundwater springs, wildlife population and endowed with notable archeologic monuments and other appealing characteristics, thus the need for a baseline survey of the physiochemical measurements to ascertain the concentrations of major cations and heavy metals (Cd, Co, Cr, Cu, Fe, Li, Mn, Ni, and Pb)), their distribution across the sampling locations and to investigate the origin of Potentially Toxic Elements (PTEs) due to threats from anthropogenic and geogenic processes to its quality to evaluating its suitability for drinking, and the risk imposed on human health through the use of Water Quality Index (WQI), Hazard Quotient (HQ) and Hazard Index (HI). Concentrations of forty-one water samples from twenty natural springs, fifteen boreholes, five hand-dug wells, and a stream a were detected. Nine heavy metals (Fe, Mn, Li, Cd, Co, Cr, Cu, Pb, and Ni) were analysed with Flame Atomic Absorption Spectrometry (FAAS) and the data using different multivariate statistical approaches. Five component types; 24.40%, 14.50%, 12.10%, 9.64% and 9.24% extracted accounted for 69.79% total variance. The dominant variables derived from PCA's five components indicated the influence of the weathering of anhydrous carbonate, which released major cations and the PTEs. Calculated HQs and HI for adults and children were generally less than one (HQ < 1), indicating less or no potential carcinogenic, except for a heavy metal Cd. It exhibits an HQ and HI > 1, for children ingesting water from all the water sources. Hand-dug wells and surface water from the stream had HQ and HI > 1 for Cd for adults, which may not be harmful but with overtime exposure and may require monitoring; otherwise, it may pose more threats to adults and children with time. Elsevier 2022 Article PeerReviewed Jabbo, Josiah Nuhu and Mohd Isa, Noorain and Aris, Ahmad Zaharin and Ramli, Mohammad Firuz and Abubakar, Mohammed Bello (2022) Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria. Journal of Cleaner Production, 330. art. no. 129916. pp. 1-12. ISSN 0959-6526 https://www.sciencedirect.com/science/article/pii/S0959652621040853 10.1016/j.jclepro.2021.129916
spellingShingle Jabbo, Josiah Nuhu
Mohd Isa, Noorain
Aris, Ahmad Zaharin
Ramli, Mohammad Firuz
Abubakar, Mohammed Bello
Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria
title Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria
title_full Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria
title_fullStr Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria
title_full_unstemmed Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria
title_short Geochemometric approach to groundwater quality and health risk assessment of heavy metals of Yankari Game Reserve and its environs, Northeast Nigeria
title_sort geochemometric approach to groundwater quality and health risk assessment of heavy metals of yankari game reserve and its environs, northeast nigeria
url http://psasir.upm.edu.my/id/eprint/101626/
http://psasir.upm.edu.my/id/eprint/101626/
http://psasir.upm.edu.my/id/eprint/101626/