Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana

A thermal behavior study of lipid-extracted Nannochloropsis gaditana (LEA) was performed in a thermogravimetric analyzer. The study was performed by heating the sample under different heating rates (5, 10, and 15 °C/min) from room temperature to 1000 °C using N2 gas as the medium. This is crucial fo...

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Main Authors: M., S. N. Atikah, W. A. K. G., Wan Azlina, Yap, Taufiq Yun Hin, Mahmoud, Omar, El-Shafay, A. S., Ilyas, R. A., Harun, Razif
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2022
Online Access:http://psasir.upm.edu.my/id/eprint/101598/
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author M., S. N. Atikah
W. A. K. G., Wan Azlina
Yap, Taufiq Yun Hin
Mahmoud, Omar
El-Shafay, A. S.
Ilyas, R. A.
Harun, Razif
author_facet M., S. N. Atikah
W. A. K. G., Wan Azlina
Yap, Taufiq Yun Hin
Mahmoud, Omar
El-Shafay, A. S.
Ilyas, R. A.
Harun, Razif
author_sort M., S. N. Atikah
building UPM Institutional Repository
collection Online Access
description A thermal behavior study of lipid-extracted Nannochloropsis gaditana (LEA) was performed in a thermogravimetric analyzer. The study was performed by heating the sample under different heating rates (5, 10, and 15 °C/min) from room temperature to 1000 °C using N2 gas as the medium. This is crucial for thermal stability studies in a kinetic control regime. The following three stages of chemical decompositions were found: (1) moisture removal (2) devolatilization (3) fixed carbon decomposition; maximum decomposition was observed at the second stage. Activation energies of the LEA were studied using the Flynn–Wall–Ozawa model and Kissinger–Akahira–Sunose model. Main sample decomposition was observed from 100–700 °C during volatile matter evaporation. The thermal behavior study findings were used for the gasification of the sample with air to study the effect of varying reaction parameters on the compositions of the synthesis gas yield. Maximum H2 yield was found at 700 °C and 0.7 g, which were 51.2 mol% and 50.6 mol%, respectively. From the study, it was found that LEA is suitable to be used as feedstock in gasification for synthesis gas production.
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institution Universiti Putra Malaysia
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publisher Multidisciplinary Digital Publishing Institute
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spelling upm-1015982023-06-16T20:26:48Z http://psasir.upm.edu.my/id/eprint/101598/ Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana M., S. N. Atikah W. A. K. G., Wan Azlina Yap, Taufiq Yun Hin Mahmoud, Omar El-Shafay, A. S. Ilyas, R. A. Harun, Razif A thermal behavior study of lipid-extracted Nannochloropsis gaditana (LEA) was performed in a thermogravimetric analyzer. The study was performed by heating the sample under different heating rates (5, 10, and 15 °C/min) from room temperature to 1000 °C using N2 gas as the medium. This is crucial for thermal stability studies in a kinetic control regime. The following three stages of chemical decompositions were found: (1) moisture removal (2) devolatilization (3) fixed carbon decomposition; maximum decomposition was observed at the second stage. Activation energies of the LEA were studied using the Flynn–Wall–Ozawa model and Kissinger–Akahira–Sunose model. Main sample decomposition was observed from 100–700 °C during volatile matter evaporation. The thermal behavior study findings were used for the gasification of the sample with air to study the effect of varying reaction parameters on the compositions of the synthesis gas yield. Maximum H2 yield was found at 700 °C and 0.7 g, which were 51.2 mol% and 50.6 mol%, respectively. From the study, it was found that LEA is suitable to be used as feedstock in gasification for synthesis gas production. Multidisciplinary Digital Publishing Institute 2022-08-03 Article PeerReviewed M., S. N. Atikah and W. A. K. G., Wan Azlina and Yap, Taufiq Yun Hin and Mahmoud, Omar and El-Shafay, A. S. and Ilyas, R. A. and Harun, Razif (2022) Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana. Processes, 10 (8). art. no. 1525. pp. 1-13. ISSN 2227-9717 https://www.mdpi.com/2227-9717/10/8/1525 10.3390/pr10081525
spellingShingle M., S. N. Atikah
W. A. K. G., Wan Azlina
Yap, Taufiq Yun Hin
Mahmoud, Omar
El-Shafay, A. S.
Ilyas, R. A.
Harun, Razif
Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana
title Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana
title_full Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana
title_fullStr Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana
title_full_unstemmed Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana
title_short Gasification characteristics and kinetics of lipid-extracted Nannochloropsis gaditana
title_sort gasification characteristics and kinetics of lipid-extracted nannochloropsis gaditana
url http://psasir.upm.edu.my/id/eprint/101598/
http://psasir.upm.edu.my/id/eprint/101598/
http://psasir.upm.edu.my/id/eprint/101598/