A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch

A facile approach for the preparation of hydrophilic starch-based spherical nanoparticles from native sago (Metroxylon sagu) starch using the drop-wise solvent exchange method was reported. Starch-maleate monoester (SM) was initially synthesized from native sago starch and maleic anhydride in an aq...

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Main Authors: Tay, S.H., Pang, S.C., Chin, S.F.
Format: Article
Language:English
Published: WILEY-VCH Verlag GmbH & Co 2012
Subjects:
Online Access:http://ir.unimas.my/id/eprint/9872/
http://ir.unimas.my/id/eprint/9872/1/A%20facile%20approach%20for%20controlled%20synthesis%20ofhydrophilic%20starch-based%20nanoparticles%20fromnative%20sago%20starch%20%28abstract%29.pdf
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author Tay, S.H.
Pang, S.C.
Chin, S.F.
author_facet Tay, S.H.
Pang, S.C.
Chin, S.F.
author_sort Tay, S.H.
building UNIMAS Institutional Repository
collection Online Access
description A facile approach for the preparation of hydrophilic starch-based spherical nanoparticles from native sago (Metroxylon sagu) starch using the drop-wise solvent exchange method was reported. Starch-maleate monoester (SM) was initially synthesized from native sago starch and maleic anhydride in an aqueous medium, and SM nanoparticles was subsequently precipitated in absolute ethanol under controlled conditions. The present study was focused mainly on modulating of the solvent and non-solvent systems to prepare SM nanoparticles of different morphologies. The pH of the solvent system and the nature of surfactants being added into the solvent system could influence the morphology of regenerated SM nanoparticles. SM nanoparticles of discrete and spherical shape were regenerated from a basic SM sample solution, or an acidic sample solution in the presence of an appropriate surfactant. SM nanoparticles with mean diameter of about 250 nm was obtained by precipitation in absolute ethanol in the presence of Brij 35 as the surfactant.
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spelling unimas-98722015-12-03T02:57:28Z http://ir.unimas.my/id/eprint/9872/ A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch Tay, S.H. Pang, S.C. Chin, S.F. QK Botany A facile approach for the preparation of hydrophilic starch-based spherical nanoparticles from native sago (Metroxylon sagu) starch using the drop-wise solvent exchange method was reported. Starch-maleate monoester (SM) was initially synthesized from native sago starch and maleic anhydride in an aqueous medium, and SM nanoparticles was subsequently precipitated in absolute ethanol under controlled conditions. The present study was focused mainly on modulating of the solvent and non-solvent systems to prepare SM nanoparticles of different morphologies. The pH of the solvent system and the nature of surfactants being added into the solvent system could influence the morphology of regenerated SM nanoparticles. SM nanoparticles of discrete and spherical shape were regenerated from a basic SM sample solution, or an acidic sample solution in the presence of an appropriate surfactant. SM nanoparticles with mean diameter of about 250 nm was obtained by precipitation in absolute ethanol in the presence of Brij 35 as the surfactant. WILEY-VCH Verlag GmbH & Co 2012 Article NonPeerReviewed text en http://ir.unimas.my/id/eprint/9872/1/A%20facile%20approach%20for%20controlled%20synthesis%20ofhydrophilic%20starch-based%20nanoparticles%20fromnative%20sago%20starch%20%28abstract%29.pdf Tay, S.H. and Pang, S.C. and Chin, S.F. (2012) A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch. Starch, 64. pp. 984-990. ISSN 1521-379X http://www.researchgate.net/publication/267870091 DOI: 10.1002/star.201200056
spellingShingle QK Botany
Tay, S.H.
Pang, S.C.
Chin, S.F.
A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch
title A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch
title_full A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch
title_fullStr A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch
title_full_unstemmed A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch
title_short A facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch
title_sort facile approach for controlled synthesis of hydrophilic starch-based nanoparticles from native sago starch
topic QK Botany
url http://ir.unimas.my/id/eprint/9872/
http://ir.unimas.my/id/eprint/9872/
http://ir.unimas.my/id/eprint/9872/
http://ir.unimas.my/id/eprint/9872/1/A%20facile%20approach%20for%20controlled%20synthesis%20ofhydrophilic%20starch-based%20nanoparticles%20fromnative%20sago%20starch%20%28abstract%29.pdf