Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV)
The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)2(C18H12N2O3)], O,N,O'-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O-Sn-O = 155.2 (2)°]. The hydroxy group is a hydrogen-bo...
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| Format: | Article |
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International Union of Crystallography
2010
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| Online Access: | http://ir.unimas.my/id/eprint/7962/ |
| _version_ | 1848836267988484096 |
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| author | Md. Abu, Affan Norrihan, Sam Fasihuddin Badruddin, Ahmad Seik Weng, N |
| author_facet | Md. Abu, Affan Norrihan, Sam Fasihuddin Badruddin, Ahmad Seik Weng, N |
| author_sort | Md. Abu, Affan |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)2(C18H12N2O3)], O,N,O'-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O-Sn-O = 155.2 (2)°]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions. |
| first_indexed | 2025-11-15T06:21:03Z |
| format | Article |
| id | unimas-7962 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| last_indexed | 2025-11-15T06:21:03Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-79622023-03-29T03:30:44Z http://ir.unimas.my/id/eprint/7962/ Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV) Md. Abu, Affan Norrihan, Sam Fasihuddin Badruddin, Ahmad Seik Weng, N QD Chemistry The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)2(C18H12N2O3)], O,N,O'-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O-Sn-O = 155.2 (2)°]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions. International Union of Crystallography 2010 Article PeerReviewed Md. Abu, Affan and Norrihan, Sam and Fasihuddin Badruddin, Ahmad and Seik Weng, N (2010) Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV). Acta Crystallographica Section E, 66 (5). m572-m572. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/05/00/bt5252/bt5252.pdf |
| spellingShingle | QD Chemistry Md. Abu, Affan Norrihan, Sam Fasihuddin Badruddin, Ahmad Seik Weng, N Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV) |
| title | Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV) |
| title_full | Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV) |
| title_fullStr | Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV) |
| title_full_unstemmed | Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV) |
| title_short | Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV) |
| title_sort | di-n-butyl{4-hydroxy-n0-[(2-oxido-1-naphthyl-jo) methylene]benzohydrazidato-j2 o,n0}tin(iv) |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/7962/ http://ir.unimas.my/id/eprint/7962/ |