Coordination chemistry of organotin (IV) complexes with bidentate and tridentate (NNNNN) donor ligands
Two ligands have been prepared by condensation reaction of 2-acetylpyridine with o-phenylenediamine and 2-acetylpyridine-o-phenylenediamine with acetophenone in 1:1 mole ratio. Organotin(IV) complexes have been synthesized where the ligands acted as bidentate N,N and tridentate N,N,N chelating agent...
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| Format: | Final Year Project Report / IMRAD |
| Language: | English |
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Universiti Malaysia Sarawak, UNIMAS
2007
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| Online Access: | http://ir.unimas.my/id/eprint/7845/ http://ir.unimas.my/id/eprint/7845/4/Imelda%20%28full%20text%29.pdf |
| Summary: | Two ligands have been prepared by condensation reaction of 2-acetylpyridine with o-phenylenediamine and 2-acetylpyridine-o-phenylenediamine with acetophenone in 1:1 mole ratio. Organotin(IV) complexes have been synthesized where the ligands acted as bidentate N,N and tridentate N,N,N chelating agents, respectively. The characterization of the ligands (1-2) and their organotin(IV) complexes (3-11) has been made on the basis of elemental analyses, UV-visible and FTIR spectra studies. On the basis of analytical and spectral data, six-membered geometry and seven-membered geometry around organotin(IV) moiety have been proposed. |
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