Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands

Four transition metal(II) complexes of each carbohydrazone-bis(2-hydroxynaphthaldehyde) (1) and pyridine-2-carboxaldehyde isonicotinichydrazone (2) ligands have been synthesized and characterized by CHN analyses, FTIR and UV-Visible spectral studies. All transition metal(II) complexes of carbohydraz...

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Main Author: Thong, Cia Ming
Format: Final Year Project Report / IMRAD
Language:English
Published: Universiti Malaysia Sarawak, UNIMAS 2009
Subjects:
Online Access:http://ir.unimas.my/id/eprint/7739/
http://ir.unimas.my/id/eprint/7739/4/Cia%20Ming%28fulltext%29.pdf
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author Thong, Cia Ming
author_facet Thong, Cia Ming
author_sort Thong, Cia Ming
building UNIMAS Institutional Repository
collection Online Access
description Four transition metal(II) complexes of each carbohydrazone-bis(2-hydroxynaphthaldehyde) (1) and pyridine-2-carboxaldehyde isonicotinichydrazone (2) ligands have been synthesized and characterized by CHN analyses, FTIR and UV-Visible spectral studies. All transition metal(II) complexes of carbohydrazone/hydrazone ligands have been analyzed by determining their molar conductivity. Two carbohydrazone/hydrazone ligands and their respective Co(II) complexes have also been characterized by 1H NMR spectral study. All transition metal(II) complexes exhibited non electrolytic properties in nature. Spectral studies indicated both of the carbohydrazone/hydrazone ligands (1-2) acted as dinegative tridentate fashion towards the transition metal(II) ions. The proposed structures of the transition metal(II) complexes have been deduced on the basis of elemental analyses and spectral studies. Therefore, a four coordinated molecular structure has been proposed for the synthesized transition metal(II) complexes.
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format Final Year Project Report / IMRAD
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institution Universiti Malaysia Sarawak
institution_category Local University
language English
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publisher Universiti Malaysia Sarawak, UNIMAS
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spelling unimas-77392024-08-27T08:25:17Z http://ir.unimas.my/id/eprint/7739/ Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands Thong, Cia Ming Q Science (General) Four transition metal(II) complexes of each carbohydrazone-bis(2-hydroxynaphthaldehyde) (1) and pyridine-2-carboxaldehyde isonicotinichydrazone (2) ligands have been synthesized and characterized by CHN analyses, FTIR and UV-Visible spectral studies. All transition metal(II) complexes of carbohydrazone/hydrazone ligands have been analyzed by determining their molar conductivity. Two carbohydrazone/hydrazone ligands and their respective Co(II) complexes have also been characterized by 1H NMR spectral study. All transition metal(II) complexes exhibited non electrolytic properties in nature. Spectral studies indicated both of the carbohydrazone/hydrazone ligands (1-2) acted as dinegative tridentate fashion towards the transition metal(II) ions. The proposed structures of the transition metal(II) complexes have been deduced on the basis of elemental analyses and spectral studies. Therefore, a four coordinated molecular structure has been proposed for the synthesized transition metal(II) complexes. Universiti Malaysia Sarawak, UNIMAS 2009 Final Year Project Report / IMRAD NonPeerReviewed text en http://ir.unimas.my/id/eprint/7739/4/Cia%20Ming%28fulltext%29.pdf Thong, Cia Ming (2009) Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands. [Final Year Project Report / IMRAD] (Unpublished)
spellingShingle Q Science (General)
Thong, Cia Ming
Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands
title Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands
title_full Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands
title_fullStr Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands
title_full_unstemmed Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands
title_short Synthesis and Characterization of Transition Metal II Complexes With Carbohydrazone-Hydrazone Ligands
title_sort synthesis and characterization of transition metal ii complexes with carbohydrazone-hydrazone ligands
topic Q Science (General)
url http://ir.unimas.my/id/eprint/7739/
http://ir.unimas.my/id/eprint/7739/4/Cia%20Ming%28fulltext%29.pdf