n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV)
Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordi...
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| Format: | Article |
| Language: | English English |
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International Union of Crystallography
2010
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| Online Access: | http://ir.unimas.my/id/eprint/7358/ http://ir.unimas.my/id/eprint/7358/1/n-Butyldichlorido%20%282-%7B%281E%29-1-%5B2-%28pyridin-2-yl%29%20hydrazin-1-ylidene%5D%20ethyl%7D%20phenolato%29%20tin%20%28IV%29%20%28abstract%29.pdf http://ir.unimas.my/id/eprint/7358/2/n-Butyldichlorido%282-%7B%281E%29-1-%5B2-%28pyridin-%28OCR%29.pdf |
| _version_ | 1848836111070134272 |
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| author | Fasihuddin Badruddin, Ahmad Md Abu, Affan Dayang NA, Chee Seik Weng, Ng Edward R. T., Tiekink |
| author_facet | Fasihuddin Badruddin, Ahmad Md Abu, Affan Dayang NA, Chee Seik Weng, Ng Edward R. T., Tiekink |
| author_sort | Fasihuddin Badruddin, Ahmad |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | Two independent molecules comprise the asymmetric unit of
the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom
in each is coordinated by the tridentate ligand via the
phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordination geometry is completed by the -C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the molecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and 64.4 (11)]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H���Cl hydrogen bonds, which link the molecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H���Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%. |
| first_indexed | 2025-11-15T06:18:34Z |
| format | Article |
| id | unimas-7358 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T06:18:34Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-73582016-04-20T00:37:01Z http://ir.unimas.my/id/eprint/7358/ n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) Fasihuddin Badruddin, Ahmad Md Abu, Affan Dayang NA, Chee Seik Weng, Ng Edward R. T., Tiekink QD Chemistry Two independent molecules comprise the asymmetric unit of the title compound, [Sn(C4H9)(C13H12N3O)Cl2]. The Sn atom in each is coordinated by the tridentate ligand via the phenoxide O, hydrazine N and pyridyl N atoms, forming fiveand six-membered chelate rings. The approximately octahedral coordination geometry is completed by the -C atom of the n-butyl group (which is trans to the hydrazine N atom) and two mutually trans Cl atoms. Differences between the molecules are evident in the relative planarity of the chelate rings and in the conformations of the n-butyl groups [C—C—C—C = 177.2 (5) and 64.4 (11)]. Significant differences in the Sn—Cl bond lengths are related to the formation of N—H���Cl hydrogen bonds, which link the molecules comprising the asymmetric unit into dimeric aggregates. These are consolidated in the crystal packing by C—H���Cl contacts. The structure was refined as an inversion twin; the minor twin component is 37 (3)%. International Union of Crystallography 2010 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7358/1/n-Butyldichlorido%20%282-%7B%281E%29-1-%5B2-%28pyridin-2-yl%29%20hydrazin-1-ylidene%5D%20ethyl%7D%20phenolato%29%20tin%20%28IV%29%20%28abstract%29.pdf text en http://ir.unimas.my/id/eprint/7358/2/n-Butyldichlorido%282-%7B%281E%29-1-%5B2-%28pyridin-%28OCR%29.pdf Fasihuddin Badruddin, Ahmad and Md Abu, Affan and Dayang NA, Chee and Seik Weng, Ng and Edward R. T., Tiekink (2010) n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV). Acta Crystallographica Section E: Structure Reports Online, 66 (11). pp. 1412-1413. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/11/00/hb5679/hb5679.pdf |
| spellingShingle | QD Chemistry Fasihuddin Badruddin, Ahmad Md Abu, Affan Dayang NA, Chee Seik Weng, Ng Edward R. T., Tiekink n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) |
| title | n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) |
| title_full | n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) |
| title_fullStr | n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) |
| title_full_unstemmed | n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) |
| title_short | n-Butyldichlorido (2-{(1E)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (IV) |
| title_sort | n-butyldichlorido (2-{(1e)-1-[2-(pyridin-2-yl) hydrazin-1-ylidene] ethyl} phenolato) tin (iv) |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/7358/ http://ir.unimas.my/id/eprint/7358/ http://ir.unimas.my/id/eprint/7358/1/n-Butyldichlorido%20%282-%7B%281E%29-1-%5B2-%28pyridin-2-yl%29%20hydrazin-1-ylidene%5D%20ethyl%7D%20phenolato%29%20tin%20%28IV%29%20%28abstract%29.pdf http://ir.unimas.my/id/eprint/7358/2/n-Butyldichlorido%282-%7B%281E%29-1-%5B2-%28pyridin-%28OCR%29.pdf |