{4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate
Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C6H5)2(C17H14N2O3)]·CH3OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2011
|
| Subjects: | |
| Online Access: | http://ir.unimas.my/id/eprint/7357/ http://ir.unimas.my/id/eprint/7357/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28abstract%29.pdf http://ir.unimas.my/id/eprint/7357/2/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28OCR%29.pdf |
| _version_ | 1848836110782824448 |
|---|---|
| author | Fasihuddin B, Ahmad Md Abu, Affan Norrihan B Sam, Sam Fraser, White Edward RT, Tiekink |
| author_facet | Fasihuddin B, Ahmad Md Abu, Affan Norrihan B Sam, Sam Fraser, White Edward RT, Tiekink |
| author_sort | Fasihuddin B, Ahmad |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C6H5)2(C17H14N2O3)]·CH3OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C2N2O donor set defines a coordination geometry that is intermediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one molecule slightly tending towards TP and the other slightly towards SP. The molecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-molecule aggregates via O-H...O and O-H...N hydrogen bonds, in which the hydroxy group is connected to a methanol molecule which, in turn, is linked to a non-coordinating N atom. Weak C-H...[pi] interactions also occur. |
| first_indexed | 2025-11-15T06:18:34Z |
| format | Article |
| id | unimas-7357 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T06:18:34Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-73572015-05-25T07:20:08Z http://ir.unimas.my/id/eprint/7357/ {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate Fasihuddin B, Ahmad Md Abu, Affan Norrihan B Sam, Sam Fraser, White Edward RT, Tiekink QD Chemistry Two independent diphenyltin molecules and two independent methanol molecules comprise the asymmetric unit of the title compound, [Sn(C6H5)2(C17H14N2O3)]·CH3OH. The Sn atom in each is five-coordinated by a tridentate ligand and the ipso-C atoms of the Sn-bound benzene substituents. The resulting C2N2O donor set defines a coordination geometry that is intermediate between trigonal-bipyramidal (TP) and square-pyramidal (SP), with one molecule slightly tending towards TP and the other slightly towards SP. The molecules differ in terms of the relative orientations of the terminal benzene rings [dihedral angles = 45.71 (18) and 53.98 (17)°] and of the Sn-bound benzene substituents [dihedral angles = 59.5 (2) and 45.77 (18)°, respectively]. The most prominent feature of the crystal packing is the formation of four-molecule aggregates via O-H...O and O-H...N hydrogen bonds, in which the hydroxy group is connected to a methanol molecule which, in turn, is linked to a non-coordinating N atom. Weak C-H...[pi] interactions also occur. International Union of Crystallography 2011 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7357/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28abstract%29.pdf text en http://ir.unimas.my/id/eprint/7357/2/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28OCR%29.pdf Fasihuddin B, Ahmad and Md Abu, Affan and Norrihan B Sam, Sam and Fraser, White and Edward RT, Tiekink (2011) {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 67 (7). m963-m964. ISSN 1600-5368 http://journals.iucr.org/e/issues/2011/07/00/hb5914/hb5914.pdf doi:10.1107/S1600536811023415 |
| spellingShingle | QD Chemistry Fasihuddin B, Ahmad Md Abu, Affan Norrihan B Sam, Sam Fraser, White Edward RT, Tiekink {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate |
| title | {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate |
| title_full | {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate |
| title_fullStr | {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate |
| title_full_unstemmed | {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate |
| title_short | {4-Hydroxy-N'-[(2E, 3Z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (IV) methanol monosolvate |
| title_sort | {4-hydroxy-n'-[(2e, 3z)-4-oxido-4-phenylbut-3-en-2-ylidene] benzohydrazidato} diphenyltin (iv) methanol monosolvate |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/7357/ http://ir.unimas.my/id/eprint/7357/ http://ir.unimas.my/id/eprint/7357/ http://ir.unimas.my/id/eprint/7357/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28abstract%29.pdf http://ir.unimas.my/id/eprint/7357/2/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%28OCR%29.pdf |