{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)

{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)

The SnIV atom in the title compound, [Sn(CH3)2- (C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra...

Full description

Bibliographic Details
Main Authors: Fasihuddin B, Ahmad, Fraser, White, MA, Affan, Edward R. T., Tiekink, Norrihan B, Sam
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://ir.unimas.my/id/eprint/7354/
http://ir.unimas.my/id/eprint/7354/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%20phenylbut-3-en-2-ylidene%5Dbenzohydrazidato%7Ddimethyltin%28IV%29.pdf
_version_ 1848836110216593408
author Fasihuddin B, Ahmad
Fraser, White
MA, Affan
Edward R. T., Tiekink
Norrihan B, Sam
author_facet Fasihuddin B, Ahmad
Fraser, White
MA, Affan
Edward R. T., Tiekink
Norrihan B, Sam
author_sort Fasihuddin B, Ahmad
building UNIMAS Institutional Repository
collection Online Access
description The SnIV atom in the title compound, [Sn(CH3)2- (C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supramolecular zigzag chains propagating along the caxis direction are mediated by O—HO hydrogen bonds, and weak C—H interactions consolidate the packing.
first_indexed 2025-11-15T06:18:33Z
format Article
id unimas-7354
institution Universiti Malaysia Sarawak
institution_category Local University
language English
last_indexed 2025-11-15T06:18:33Z
publishDate 2011
publisher International Union of Crystallography
recordtype eprints
repository_type Digital Repository
spelling unimas-73542015-05-25T07:05:44Z http://ir.unimas.my/id/eprint/7354/ {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) Fasihuddin B, Ahmad Fraser, White MA, Affan Edward R. T., Tiekink Norrihan B, Sam QD Chemistry The SnIV atom in the title compound, [Sn(CH3)2- (C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supramolecular zigzag chains propagating along the caxis direction are mediated by O—HO hydrogen bonds, and weak C—H interactions consolidate the packing. International Union of Crystallography 2011 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7354/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%20phenylbut-3-en-2-ylidene%5Dbenzohydrazidato%7Ddimethyltin%28IV%29.pdf Fasihuddin B, Ahmad and Fraser, White and MA, Affan and Edward R. T., Tiekink and Norrihan B, Sam (2011) {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 67 (7). m965-m965. ISSN 1600-5368 http://journals.iucr.org/e/issues/2011/07/00/hb5915/hb5915.pdf 10.1107/S1600536811023
spellingShingle QD Chemistry
Fasihuddin B, Ahmad
Fraser, White
MA, Affan
Edward R. T., Tiekink
Norrihan B, Sam
{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
title {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
title_full {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
title_fullStr {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
title_full_unstemmed {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
title_short {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
title_sort {4-hydroxy-n0-[(2e,3z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(iv)
topic QD Chemistry
url http://ir.unimas.my/id/eprint/7354/
http://ir.unimas.my/id/eprint/7354/
http://ir.unimas.my/id/eprint/7354/
http://ir.unimas.my/id/eprint/7354/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%20phenylbut-3-en-2-ylidene%5Dbenzohydrazidato%7Ddimethyltin%28IV%29.pdf

Similar Items