Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)

The SnIV atom in the title compound, [Sn(C6H5)(C14H19- N4S)Cl2], exists within a distorted octahedral geometry defined by the N,N0 ,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the azo-N ato...

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Main Authors:	Fasihuddin B., Ahmad, Md. Abdus, Salam, Md. Abu, Affan, M. Ibrahim Mohamed, Tahir, Edward R. T., Tiekink
Format:	Article
Language:	English
Published:	International Union of Crystallography 2010
Subjects:	QD Chemistry
Online Access:	http://ir.unimas.my/id/eprint/7335/ http://ir.unimas.my/id/eprint/7335/1/Dichlorido.pdf

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author	Fasihuddin B., Ahmad Md. Abdus, Salam Md. Abu, Affan M. Ibrahim Mohamed, Tahir Edward R. T., Tiekink
author_facet	Fasihuddin B., Ahmad Md. Abdus, Salam Md. Abu, Affan M. Ibrahim Mohamed, Tahir Edward R. T., Tiekink
author_sort	Fasihuddin B., Ahmad
building	UNIMAS Institutional Repository
collection	Online Access
description	The SnIV atom in the title compound, [Sn(C6H5)(C14H19- N4S)Cl2], exists within a distorted octahedral geometry defined by the N,N0 ,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.03 (4)]. With the exception of the cyclohexyl group (chair form), the Schiff base ligand is almost planar (r.m.s. deviation of non-H and Sn atoms = 0.053 A˚ ). The nearly orthogonal orientation of the Sn-bound phenyl group [N—Sn—C—C torsion angle = 70.8 (5)] to the planar portion of the Schiff base allows for the formation of significant intramolecular C—HCl interactions which preclude the Cl atoms from participating in N—HCl hydrogen bonds. Instead, C—H contacts, involving methylene H and the Sn-bound phenyl group, lead to the formation of supramolecular chains that pack in the bc plane. Connections between these layers are of the type C—HCl.
first_indexed	2025-11-15T06:18:30Z
format	Article
id	unimas-7335
institution	Universiti Malaysia Sarawak
institution_category	Local University
language	English
last_indexed	2025-11-15T06:18:30Z
publishDate	2010
publisher	International Union of Crystallography
recordtype	eprints
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spelling	unimas-73352015-05-05T06:33:59Z http://ir.unimas.my/id/eprint/7335/ Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV) Fasihuddin B., Ahmad Md. Abdus, Salam Md. Abu, Affan M. Ibrahim Mohamed, Tahir Edward R. T., Tiekink QD Chemistry The SnIV atom in the title compound, [Sn(C6H5)(C14H19- N4S)Cl2], exists within a distorted octahedral geometry defined by the N,N0 ,S-tridentate monodeprotonated Schiff base ligand, two mutually trans Cl atoms, and the ipso-C atom of the Sn-bound phenyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.03 (4)]. With the exception of the cyclohexyl group (chair form), the Schiff base ligand is almost planar (r.m.s. deviation of non-H and Sn atoms = 0.053 A˚ ). The nearly orthogonal orientation of the Sn-bound phenyl group [N—Sn—C—C torsion angle = 70.8 (5)] to the planar portion of the Schiff base allows for the formation of significant intramolecular C—HCl interactions which preclude the Cl atoms from participating in N—HCl hydrogen bonds. Instead, C—H contacts, involving methylene H and the Sn-bound phenyl group, lead to the formation of supramolecular chains that pack in the bc plane. Connections between these layers are of the type C—HCl. International Union of Crystallography 2010 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7335/1/Dichlorido.pdf Fasihuddin B., Ahmad and Md. Abdus, Salam and Md. Abu, Affan and M. Ibrahim Mohamed, Tahir and Edward R. T., Tiekink (2010) Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (12). o1503-o1504. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/12/00/hb5715/hb5715.pdf doi:10.1107/S1600536810044
spellingShingle	QD Chemistry Fasihuddin B., Ahmad Md. Abdus, Salam Md. Abu, Affan M. Ibrahim Mohamed, Tahir Edward R. T., Tiekink Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)
title	Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)
title_full	Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)
title_fullStr	Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)
title_full_unstemmed	Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)
title_short	Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)
title_sort	dichlorido{4-cyclohexyl-1-[1-(2- hyridyljn)ethylidene]thiosemicarbazidatoj2 n1 ,s}phenyltin(iv)
topic	QD Chemistry
url	http://ir.unimas.my/id/eprint/7335/ http://ir.unimas.my/id/eprint/7335/ http://ir.unimas.my/id/eprint/7335/ http://ir.unimas.my/id/eprint/7335/1/Dichlorido.pdf

Dichlorido{4-cyclohexyl-1-[1-(2- hyridyljN)ethylidene]thiosemicarbazidatoj2 N1 ,S}phenyltin(IV)

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