{4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)

{4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)

Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)2- (C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geom...

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Main Authors: Fasihuddin B, Ahmad, Md Abu, Affan, Norrihan B, Sam, Edward RT, Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://ir.unimas.my/id/eprint/7332/
http://ir.unimas.my/id/eprint/7332/1/%7B4-Hydroxy-N%27-%5B%282-oxido-1-naphthyl-O%29%20methylidene%5D%20benzohydrazidato-2N%27%2C%20O%7D%20dimethyltin%20%28IV%29.pdf
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author Fasihuddin B, Ahmad
Md Abu, Affan
Norrihan B, Sam
Edward RT, Tiekink
author_facet Fasihuddin B, Ahmad
Md Abu, Affan
Norrihan B, Sam
Edward RT, Tiekink
author_sort Fasihuddin B, Ahmad
building UNIMAS Institutional Repository
collection Online Access
description Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)2- (C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. +Zigzag chains running along the a axis mediated by O—HN hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C—HN and – [centroid–centroid distances = 3.658 (2) and 3.6740 (18) A˚ ] interactions. The layers are connected along the c axis via C—HO interactions.
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institution Universiti Malaysia Sarawak
institution_category Local University
language English
last_indexed 2025-11-15T06:18:29Z
publishDate 2010
publisher International Union of Crystallography
recordtype eprints
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spelling unimas-73322015-05-05T02:55:26Z http://ir.unimas.my/id/eprint/7332/ {4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV) Fasihuddin B, Ahmad Md Abu, Affan Norrihan B, Sam Edward RT, Tiekink QD Chemistry Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Sn(CH3)2- (C18H12N2O3)]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C2NO2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-pyramidal, with a small tendency towards the former. +Zigzag chains running along the a axis mediated by O—HN hydrogen bonding characterize the crystal packing. These are connected into layers in the ab plane by a combination of C—HN and – [centroid–centroid distances = 3.658 (2) and 3.6740 (18) A˚ ] interactions. The layers are connected along the c axis via C—HO interactions. International Union of Crystallography 2010 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7332/1/%7B4-Hydroxy-N%27-%5B%282-oxido-1-naphthyl-O%29%20methylidene%5D%20benzohydrazidato-2N%27%2C%20O%7D%20dimethyltin%20%28IV%29.pdf Fasihuddin B, Ahmad and Md Abu, Affan and Norrihan B, Sam and Edward RT, Tiekink (2010) {4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV). Acta Crystallographica Section E: Structure Reports Online, 66 (8). p. 924. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/08/00/bt5292/bt5292.pdf doi:10.1107/S1600536810027078
spellingShingle QD Chemistry
Fasihuddin B, Ahmad
Md Abu, Affan
Norrihan B, Sam
Edward RT, Tiekink
{4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)
title {4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)
title_full {4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)
title_fullStr {4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)
title_full_unstemmed {4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)
title_short {4-Hydroxy-N'-[(2-oxido-1-naphthyl-O) methylidene] benzohydrazidato-2N', O} dimethyltin (IV)
title_sort {4-hydroxy-n'-[(2-oxido-1-naphthyl-o) methylidene] benzohydrazidato-2n', o} dimethyltin (iv)
topic QD Chemistry
url http://ir.unimas.my/id/eprint/7332/
http://ir.unimas.my/id/eprint/7332/
http://ir.unimas.my/id/eprint/7332/
http://ir.unimas.my/id/eprint/7332/1/%7B4-Hydroxy-N%27-%5B%282-oxido-1-naphthyl-O%29%20methylidene%5D%20benzohydrazidato-2N%27%2C%20O%7D%20dimethyltin%20%28IV%29.pdf

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