Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone
Six new organotin(IV) complexes were synthesized by direct reaction of RSnCl3 (R = Me, Bu and Ph) or R2SnCl2 (R = Me, Bu and Ph) and 2-hydroxyacetophenone thiocarbohydrazone [H2APTC] under purified nitrogen in the presence of base in 1 : 2 : 1 molar ratio (metal: base: ligand). Complexes 2–7 have be...
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| Format: | Article |
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Taylor & Francis Group
2011
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| Online Access: | http://ir.unimas.my/id/eprint/7327/ |
| _version_ | 1848836104948547584 |
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| author | Fasihuddin Badruddin, Ahmad Dayang NA, Chee Md. Abu, Affan MR, Asarud Norrihan, Sam MA, Salam Ahmad, Ismail SH, Tan |
| author_facet | Fasihuddin Badruddin, Ahmad Dayang NA, Chee Md. Abu, Affan MR, Asarud Norrihan, Sam MA, Salam Ahmad, Ismail SH, Tan |
| author_sort | Fasihuddin Badruddin, Ahmad |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | Six new organotin(IV) complexes were synthesized by direct reaction of RSnCl3 (R = Me, Bu and Ph) or R2SnCl2 (R = Me, Bu and Ph) and 2-hydroxyacetophenone thiocarbohydrazone [H2APTC] under purified nitrogen in the presence of base in 1 : 2 : 1 molar ratio (metal: base: ligand). Complexes 2–7 have been characterized by elemental analyses, molar conductivity, UV-Visible, IR and 1H NMR spectral studies. Complexes 2–7 are non-electrolytes. The molecular structure of [Me2Sn(APTC)] · (C2H5OH) (5) has been determined by X-ray diffraction analysis. The thiocarbohydrazone ligand (1) and 2–7 have been tested for antibacterial activity against Escherichia coli, Staphylococcus aureus, Salmonella typhi and Enterococci aeruginosa. |
| first_indexed | 2025-11-15T06:18:28Z |
| format | Article |
| id | unimas-7327 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| last_indexed | 2025-11-15T06:18:28Z |
| publishDate | 2011 |
| publisher | Taylor & Francis Group |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-73272016-04-20T00:38:19Z http://ir.unimas.my/id/eprint/7327/ Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone Fasihuddin Badruddin, Ahmad Dayang NA, Chee Md. Abu, Affan MR, Asarud Norrihan, Sam MA, Salam Ahmad, Ismail SH, Tan QD Chemistry Six new organotin(IV) complexes were synthesized by direct reaction of RSnCl3 (R = Me, Bu and Ph) or R2SnCl2 (R = Me, Bu and Ph) and 2-hydroxyacetophenone thiocarbohydrazone [H2APTC] under purified nitrogen in the presence of base in 1 : 2 : 1 molar ratio (metal: base: ligand). Complexes 2–7 have been characterized by elemental analyses, molar conductivity, UV-Visible, IR and 1H NMR spectral studies. Complexes 2–7 are non-electrolytes. The molecular structure of [Me2Sn(APTC)] · (C2H5OH) (5) has been determined by X-ray diffraction analysis. The thiocarbohydrazone ligand (1) and 2–7 have been tested for antibacterial activity against Escherichia coli, Staphylococcus aureus, Salmonella typhi and Enterococci aeruginosa. Taylor & Francis Group 2011 Article PeerReviewed Fasihuddin Badruddin, Ahmad and Dayang NA, Chee and Md. Abu, Affan and MR, Asarud and Norrihan, Sam and MA, Salam and Ahmad, Ismail and SH, Tan (2011) Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone. Journal of Coordination Chemistry, 64 (23). 4191 -4200. ISSN 0095-8972 http://www.tandfonline.com/doi/abs/10.1080/00958972.2011.631532# DOI:10.1080/00958972.2011.631532 |
| spellingShingle | QD Chemistry Fasihuddin Badruddin, Ahmad Dayang NA, Chee Md. Abu, Affan MR, Asarud Norrihan, Sam MA, Salam Ahmad, Ismail SH, Tan Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone |
| title | Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone |
| title_full | Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone |
| title_fullStr | Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone |
| title_full_unstemmed | Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone |
| title_short | Synthesis, characterization, and antibacterial activity of organotin (IV) complexes with 2-hydroxyacetophenone thiocarbohydrazone |
| title_sort | synthesis, characterization, and antibacterial activity of organotin (iv) complexes with 2-hydroxyacetophenone thiocarbohydrazone |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/7327/ http://ir.unimas.my/id/eprint/7327/ http://ir.unimas.my/id/eprint/7327/ |