1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
In the title compound, C17H18N4O2S·H2O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O-H...S and O-H...N...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://ir.unimas.my/id/eprint/7325/ http://ir.unimas.my/id/eprint/7325/1/1%2C5-Bis.pdf |
| _version_ | 1848836104683257856 |
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| author | Fasihuddin B, Ahmad Md Abu, Affan Dayang NA, Chee Edward RT, Tiekink |
| author_facet | Fasihuddin B, Ahmad Md Abu, Affan Dayang NA, Chee Edward RT, Tiekink |
| author_sort | Fasihuddin B, Ahmad |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | In the title compound, C17H18N4O2S·H2O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O-H...S and O-H...N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of Owater-H...Ohydroxyl, N-H...Owater and Owater-H...S hydrogen bonds and C-H...[pi] interactions. |
| first_indexed | 2025-11-15T06:18:28Z |
| format | Article |
| id | unimas-7325 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T06:18:28Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-73252015-05-05T03:09:26Z http://ir.unimas.my/id/eprint/7325/ 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate Fasihuddin B, Ahmad Md Abu, Affan Dayang NA, Chee Edward RT, Tiekink QD Chemistry In the title compound, C17H18N4O2S·H2O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O-H...S and O-H...N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of Owater-H...Ohydroxyl, N-H...Owater and Owater-H...S hydrogen bonds and C-H...[pi] interactions. International Union of Crystallography 2010 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7325/1/1%2C5-Bis.pdf Fasihuddin B, Ahmad and Md Abu, Affan and Dayang NA, Chee and Edward RT, Tiekink (2010) 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). o555 - o555. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/03/00/hb5327/hb5327.pdf 10.1107/S1600536810004 |
| spellingShingle | QD Chemistry Fasihuddin B, Ahmad Md Abu, Affan Dayang NA, Chee Edward RT, Tiekink 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
| title | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide
monohydrate |
| title_full | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide
monohydrate |
| title_fullStr | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide
monohydrate |
| title_full_unstemmed | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide
monohydrate |
| title_short | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide
monohydrate |
| title_sort | 1,5-bis[(e)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide
monohydrate |
| topic | QD Chemistry |
| url | http://ir.unimas.my/id/eprint/7325/ http://ir.unimas.my/id/eprint/7325/ http://ir.unimas.my/id/eprint/7325/ http://ir.unimas.my/id/eprint/7325/1/1%2C5-Bis.pdf |