Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) ha...
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| Format: | Article |
| Language: | English |
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Elsevier
2011
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| Online Access: | http://ir.unimas.my/id/eprint/7106/ http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf |
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| author | Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali |
| author_facet | Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali |
| author_sort | Md. Abu, Affan |
| building | UNIMAS Institutional Repository |
| collection | Online Access |
| description | The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2),
[PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1 H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å,c = 9.4353(2) Å. |
| first_indexed | 2025-11-15T06:17:44Z |
| format | Article |
| id | unimas-7106 |
| institution | Universiti Malaysia Sarawak |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T06:17:44Z |
| publishDate | 2011 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | unimas-71062022-03-22T07:03:06Z http://ir.unimas.my/id/eprint/7106/ Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali QK Botany SB Plant culture SD Forestry The reaction of 2-benzoylpyridine-N(4) cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1 H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å,c = 9.4353(2) Å. Elsevier 2011 Article PeerReviewed text en http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf Md. Abu, Affan and M.A., Salam and Fasihuddin B., Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Hapipah M., Ali (2011) Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta, 366 (1). pp. 227-232. ISSN 0020-1693 doi:10.1016/j.ica.2010.11.002 |
| spellingShingle | QK Botany SB Plant culture SD Forestry Md. Abu, Affan M.A., Salam Fasihuddin B., Ahmad Ismail, Jusoh Mustaffa B., Shamsuddin Hapipah M., Ali Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] |
| title | Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_full | Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_fullStr | Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_full_unstemmed | Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_short | Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] |
| title_sort | synthesis and spectroscopic characterization of organotin(iv) complexes with 2-benzoylpyridine-n(4)-cyclohexylthiosemicarbazone (hbpct): x-ray crystal structure of [phsncl2(bpct)] |
| topic | QK Botany SB Plant culture SD Forestry |
| url | http://ir.unimas.my/id/eprint/7106/ http://ir.unimas.my/id/eprint/7106/ http://ir.unimas.my/id/eprint/7106/1/M.A.%20Affan.pdf |