Effect of sugars on the thermal and rheological properties of sago starch

Studies have been undertaken to investigate the effect of sugars on the thermal and rheological properties of sago starch. Sugars were found to increase the gelatinization temperature Tgel, and gelatinization enthalpy ΔH. Tgel and ΔH increased in the following order: control (water alone) < ribos...

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Main Authors: Fasihuddin B., Ahmad, Peter A., Williams
Format: Article
Published: John Wiley & Sons Ltd 1999
Subjects:
Online Access:http://ir.unimas.my/id/eprint/7053/
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author Fasihuddin B., Ahmad
Peter A., Williams
author_facet Fasihuddin B., Ahmad
Peter A., Williams
author_sort Fasihuddin B., Ahmad
building UNIMAS Institutional Repository
collection Online Access
description Studies have been undertaken to investigate the effect of sugars on the thermal and rheological properties of sago starch. Sugars were found to increase the gelatinization temperature Tgel, and gelatinization enthalpy ΔH. Tgel and ΔH increased in the following order: control (water alone) < ribose < fructose < glucose < maltose < sucrose. The increase in ΔH was greater for 50% starch compared to 10% starch samples. The swelling factors in the presence of sugar were higher compared to the control for sugar concentrations below 25% but were lower at sugar concentration greater than 25%. These effects are discussed in terms of the antiplaticizing effect of the sugars compared to water, the influence of sugar–starch interactions and also the effect of the sugars on water structure. The storage modulus G′, the rate constant of gelation k, and the gel strength were significantly reduced in the presence of sugars. Generally G′ and k decreased in the following order: control (water alone) > hexose > disaccharide > pentoses. This has been attributed to the reduced proportion of amylose leached following gelatinizatison. In the presence of hexoses the freeze–thaw stability of starch gels decreased while in the presence of disaccharides and pentoses the freeze–thaw stability was slightly improved. © 1999 John Wiley & Sons, Inc. Biopoly 50: 401–412, 1999
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spelling unimas-70532015-04-22T07:32:22Z http://ir.unimas.my/id/eprint/7053/ Effect of sugars on the thermal and rheological properties of sago starch Fasihuddin B., Ahmad Peter A., Williams S Agriculture (General) Studies have been undertaken to investigate the effect of sugars on the thermal and rheological properties of sago starch. Sugars were found to increase the gelatinization temperature Tgel, and gelatinization enthalpy ΔH. Tgel and ΔH increased in the following order: control (water alone) < ribose < fructose < glucose < maltose < sucrose. The increase in ΔH was greater for 50% starch compared to 10% starch samples. The swelling factors in the presence of sugar were higher compared to the control for sugar concentrations below 25% but were lower at sugar concentration greater than 25%. These effects are discussed in terms of the antiplaticizing effect of the sugars compared to water, the influence of sugar–starch interactions and also the effect of the sugars on water structure. The storage modulus G′, the rate constant of gelation k, and the gel strength were significantly reduced in the presence of sugars. Generally G′ and k decreased in the following order: control (water alone) > hexose > disaccharide > pentoses. This has been attributed to the reduced proportion of amylose leached following gelatinizatison. In the presence of hexoses the freeze–thaw stability of starch gels decreased while in the presence of disaccharides and pentoses the freeze–thaw stability was slightly improved. © 1999 John Wiley & Sons, Inc. Biopoly 50: 401–412, 1999 John Wiley & Sons Ltd 1999 Article PeerReviewed Fasihuddin B., Ahmad and Peter A., Williams (1999) Effect of sugars on the thermal and rheological properties of sago starch. Biopolymers, 50 (4). pp. 401-412. ISSN 1097-0282 http://www.researchgate.net/publication/12875140_Effect_of_sugars_on_the_thermal_and_rheological_properties_of_sago_starch DOI: 10.1002/(SICI)1097-0282(19991005)50:4<401::AID-BIP6>3.0.CO;2-V
spellingShingle S Agriculture (General)
Fasihuddin B., Ahmad
Peter A., Williams
Effect of sugars on the thermal and rheological properties of sago starch
title Effect of sugars on the thermal and rheological properties of sago starch
title_full Effect of sugars on the thermal and rheological properties of sago starch
title_fullStr Effect of sugars on the thermal and rheological properties of sago starch
title_full_unstemmed Effect of sugars on the thermal and rheological properties of sago starch
title_short Effect of sugars on the thermal and rheological properties of sago starch
title_sort effect of sugars on the thermal and rheological properties of sago starch
topic S Agriculture (General)
url http://ir.unimas.my/id/eprint/7053/
http://ir.unimas.my/id/eprint/7053/
http://ir.unimas.my/id/eprint/7053/